Application of Bis-Sulfonamides in Asymmetric Catalysis. Addition of Diethylzinc to Prochiral Aldehydes

被引:0
|
作者
F. Lake
C. Moberg
机构
[1] Royal Institute of Technology,Department of Chemistry, Organic Chemistry
来源
关键词
Alcohol; Organic Chemistry; Catalysis; Aldehyde; Secondary Alcohol;
D O I
暂无
中图分类号
学科分类号
摘要
The review summarizes the authors' and published data on the Ti(OPr-i)4-catalyzed addition of diethylzinc to prochiral aldehydes in the presence of bis-sulfonamides. The effect of bis-sulfonamide structure and other factors on the enantioselectivity of formation of secondary alcohols is discussed.
引用
收藏
页码:436 / 452
页数:16
相关论文
共 50 条
  • [41] Synthesis and application of oxadiazines as chiral ligands for the enantioselective addition of diethylzinc to aldehydes
    Dean, Melissa A.
    Hitchcock, Shawn R.
    TETRAHEDRON-ASYMMETRY, 2010, 21 (20) : 2471 - 2478
  • [42] CATALYTIC ENANTIOSELECTIVE ADDITION OF DIETHYLZINC TO ALDEHYDES - APPLICATION OF A NEW BICYCLIC CATALYST
    WALLBAUM, S
    MARTENS, J
    TETRAHEDRON-ASYMMETRY, 1993, 4 (04) : 637 - 640
  • [43] The application of chiral amino thiols as catalysts in the enantioselective addition of diethylzinc to aldehydes
    Tseng, SL
    Yang, TK
    TETRAHEDRON-ASYMMETRY, 2004, 15 (21) : 3375 - 3380
  • [44] Asymmetric addition of diethylzinc to aldehydes catalyzed by β-amino alcohols derived from limonene oxide
    Steiner, D
    Sethofer, SG
    Goralski, CT
    Singaram, B
    TETRAHEDRON-ASYMMETRY, 2002, 13 (14) : 1477 - 1483
  • [45] Effect of spacers on the activity of soluble polymer supported catalysts for the asymmetric addition of diethylzinc to aldehydes
    Anyanwu, UK
    Venkataraman, D
    TETRAHEDRON LETTERS, 2003, 44 (34) : 6445 - 6448
  • [46] Synthesis of chiral ferrocenyl aziridino alcohols and use in the catalytic asymmetric addition of diethylzinc to aldehydes
    Wang, MC
    Liu, LT
    Zhang, JS
    Shi, YY
    Wang, DK
    TETRAHEDRON-ASYMMETRY, 2004, 15 (24) : 3853 - 3859
  • [47] Structural probing of D-fructose derived ligands for asymmetric addition of diethylzinc to aldehydes
    Huang, HM
    Chen, HL
    Hu, XQ
    Bai, CM
    Zheng, Z
    TETRAHEDRON-ASYMMETRY, 2003, 14 (03) : 297 - 304
  • [48] Novel Chiral Ferrocenyl Aziridino Alcohol Catalysts Promoting Asymmetric Addition of Diethylzinc to Aldehydes
    王敏灿
    王德坤
    娄建平
    华远照
    Chinese Journal of Chemistry, 2004, (06) : 512 - 514
  • [49] Chiral Porous TADDOL-Embedded Organic Polymers for Asymmetric Diethylzinc Addition to Aldehydes
    Wang, Xiuren
    Zhang, Jie
    Liu, Yan
    Cui, Yong
    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 2014, 87 (03) : 435 - 440
  • [50] Novel chiral ferrocenyl aziridino alcohol catalysts promoting asymmetric addition of diethylzinc to aldehydes
    Wang, MC
    Wang, DK
    Lou, JP
    Hua, YZ
    CHINESE JOURNAL OF CHEMISTRY, 2004, 22 (06) : 512 - 514