Application of Bis-Sulfonamides in Asymmetric Catalysis. Addition of Diethylzinc to Prochiral Aldehydes

被引:0
|
作者
F. Lake
C. Moberg
机构
[1] Royal Institute of Technology,Department of Chemistry, Organic Chemistry
来源
关键词
Alcohol; Organic Chemistry; Catalysis; Aldehyde; Secondary Alcohol;
D O I
暂无
中图分类号
学科分类号
摘要
The review summarizes the authors' and published data on the Ti(OPr-i)4-catalyzed addition of diethylzinc to prochiral aldehydes in the presence of bis-sulfonamides. The effect of bis-sulfonamide structure and other factors on the enantioselectivity of formation of secondary alcohols is discussed.
引用
收藏
页码:436 / 452
页数:16
相关论文
共 50 条
  • [31] Novel polymer-supported chiral catalysts for the asymmetric addition of diethylzinc to aldehydes
    Wang, Su-Xi
    Chen, Fen-Er
    CHEMICAL & PHARMACEUTICAL BULLETIN, 2007, 55 (07) : 1011 - 1013
  • [32] Helical silica immobilizing ruthenium complexes for highly asymmetric addition of diethylzinc to aldehydes
    Li, Le
    Guan, Fang
    Li, Xiaoyong
    Fan, Chao
    Zheng, Aqun
    Huang, Benhua
    Zhang, Junjie
    Sun, Yang
    JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2016, 414 : 167 - 176
  • [33] Asymmetric addition of diethylzinc to aromatic aldehydes by chiral ferrocene-based catalysts
    Kim, TJ
    Lee, HY
    Ryu, ES
    Park, DK
    Cho, CS
    Shim, SC
    Jeong, JH
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2002, 649 (02) : 258 - 267
  • [34] Novel polymer-bound aminoalcohol ligands for the asymmetric addition of diethylzinc to aldehydes
    Page, Philip C. Bulman
    Allin, Steven M.
    Dilly, Suzanne J.
    Buckley, Benjamin R.
    SYNTHETIC COMMUNICATIONS, 2007, 37 (12) : 2019 - 2030
  • [35] N-Pyridylmethylephedrine derivatives in the catalytic asymmetric addition of diethylzinc to aldehydes and diphenylphosphinoylimines
    Banerjee, Sucharita
    Groeper, Jonathan A.
    Standard, Jean M.
    Hitchcock, Shawn R.
    TETRAHEDRON-ASYMMETRY, 2009, 20 (18) : 2154 - 2161
  • [36] Synthesis of 3 or 3,3′-substituted BINOL ligands and their application in the asymmetric addition of diethylzinc to aromatic aldehydes
    Guo, QS
    Liu, B
    Lu, YN
    Jiang, FY
    Song, HB
    Li, JS
    TETRAHEDRON-ASYMMETRY, 2005, 16 (22) : 3667 - 3671
  • [37] Chiral ligand 2-(2′-piperidinyl)pyridine:: synthesis, resolution and application in asymmetric diethylzinc addition to aldehydes
    Cheng, Yan-Qin
    Bian, Zheng
    Kang, Chuan-Qing
    Guo, Hai-Quan
    Gao, Lian-Xun
    TETRAHEDRON-ASYMMETRY, 2008, 19 (13) : 1572 - 1575
  • [38] The synthesis of silica-supported chiral BINOL: Application in Ti-catalyzed asymmetric addition of diethylzinc to aldehydes
    Pathak, Kavita
    Ahmad, Irshad
    Abdi, Sayed H. R.
    Kureshy, Rukhsana I.
    Khan, Noor-ul H.
    Jasra, Raksh V.
    JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2008, 280 (1-2) : 106 - 114
  • [39] Asymmetric addition of diethylzinc to aldehydes catalyzed by new zinc-amides prepared by a rhodium-catalyzed asymmetric addition
    Yoshida, Kazuhiro
    Akashi, Naohisa
    Yanagisawa, Akira
    TETRAHEDRON-ASYMMETRY, 2011, 22 (11) : 1225 - 1230
  • [40] Synthesis of C2-symmetrical bis-β-amino alcohols and their application in the enantioselective addition of diethylzinc to aldehydes
    Xu, QY
    Wang, H
    Pan, XF
    Chan, ASC
    Yang, TK
    TETRAHEDRON LETTERS, 2001, 42 (35) : 6171 - 6173