Synthesis and crystal structures of ruthenium(II) complexes with polypyridyl: [Ru(bpy)2(AFO)](ClO4)2 · H2O and [Ru(dmp)2 (AFO)](ClO4)2 · 1/2DMF · 1/2MeCN

被引：0

作者：

Guang Yang

Liang-Nian Ji

Xiang-Ge Zhou

Zhong-Yuan Zhou

机构：

[1] Zhongshan University,Department of Chemistry

[2] Chengdu Institute of Organic Chemistry,undefined

[3] Chinese Academy of Science,undefined

来源：

Transition Metal Chemistry | 1998年 / 23卷

关键词：

Physical Chemistry; Crystal Structure; Inorganic Chemistry; Catalysis; Ruthenium;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

Two ruthenium(II) complexes with polypyridyl ligands, [Ru(bpy)2(AFO)](ClO4)2 · H2O (1) and [Ru(dmp)2 (AFO)](ClO4)2 · 1/2DMF · 1/2MeCN (2) (bpy = 2,2′-bipyridine; dmp = 2,9-dimethyl-1,10-phenanthroline; AFO = 4,5-diazafluoren-9-one; DMF = N,N-dimethylformamide), were synthesized and characterized by elemental analyses, i.r. and u.v.-vis. spectra. The structures of the two complexes were determined by single crystal X-ray diffraction techniques. To relieve ligand interaction, the coordination sphere is distorted so as to form specific angles (δ) between the polypyridyl ligand planes and coordination planes (N-Ru-N).

引用

页码：273 / 276

页数：3

共 50 条

[11] Perchlorato complexes of rare-earth elements:: Syntheses and crystal structures of Lu(ClO4)3 • 3H2O, Er(ClO4)3 • H2O, and Sc(OH)(ClO4)2 • H2O
Wickleder, MS
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1999, 625 (09): : 1556 - 1561
[12] Three-dimensional structure constructed via hydrogen bonds and π-π stacking interaction.: Crystal structure of [Cu(AFO)2(H2O)2](ClO4)2•2(AFO)•2H2O (AFO=4,5-diazafluoren-9-one)
Yang, G
Yu, XL
Chen, XM
Ji, LN
CRYSTAL RESEARCH AND TECHNOLOGY, 2000, 35 (08) : 993 - 1000
[13] REACTIONS OF CATIONIC HYDRIDO COMPLEXES [RU(CO)H(MECN)2(PPH3)2]CLO4, [RU(CO)H(MECN)2(PPH3)2]PF6 WITH ALKYNES - THE CRYSTAL-STRUCTURE OF [RU(CO)(MEOOCC=CHCOOME)(MECN)2(PPH3)2]CLO4
LOPEZ, J
ROMERO, A
SANTOS, A
VEGAS, A
ECHAVARREN, AM
NOHEDA, P
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1989, 373 (02) : 249 - 258
[14] STRUCTURAL VARIATIONS IN MACROCYCLIC COPPER(II) COMPLEXES - CRYSTAL AND MOLECULAR-STRUCTURES OF [CU(CYCLOPS)H2O](CLO4) AND [CU(PREH)H2O](CLO4).H2O
ANDERSON, OP
PACKARD, AB
INORGANIC CHEMISTRY, 1979, 18 (07) : 1940 - 1947
[15] Syntheses and DNA-binding studies of two ruthenium(II) complexes containing one ancillary ligand of bpy or phen:: [Ru(bpy)(pp[2,3]p)2](ClO4)2 and [Ru(phen)(pp[2,3]p)2](ClO4)2
Wu, BY
Gao, LH
Duan, ZM
Wang, KZ
JOURNAL OF INORGANIC BIOCHEMISTRY, 2005, 99 (08) : 1685 - 1691
[16] Preparation and crystal structure of [Ag(TO)2]ClO4•H2O
Zhang, JG
Zhang, TL
Lu, Z
Yu, KB
ACTA CHIMICA SINICA, 1999, 57 (11) : 1233 - 1238
[17] New supramolecular complexes of manganese(II) and cobalt(II) with nucleic bases.: Crystal structures of [M(H2O)6(1-Mecyt)6][ClO4]2•H2O, [Co(1-Mecyt)4][ClO4]2 and [M(H2O)4(cyt)2][ClO4]2•2cyt•2H2O [M = CoII or MnII; cyt = cytosine; 1-Mecyt=1-methylcytosine]
De Munno, G
Medaglia, M
Armentano, D
Anastassopoulou, J
Theophanides, T
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2000, (10): : 1625 - 1629
[18] Photoinduced cleavage and DNA-binding of the Ruthenium(II) polypyridyl complex [Ru(phen)2(ipbd)](ClO4)2
Liu, Yun-Jun
Wang, Na
Mei, Wen-Jie
Chen, Fei
He, Li-Xin
Jian, Liu-Qing
Wang, Rui-Jie
Wu, Fu-Hai
TRANSITION METAL CHEMISTRY, 2007, 32 (03) : 332 - 337
[19] Photoinduced cleavage and DNA-binding of the Ruthenium(II) polypyridyl complex [Ru(phen)2(ipbd)](ClO4)2
Yun-Jun Liu
Na Wang
Wen-Jie Mei
Fei Chen
Li-Xin He
Liu-Qing Jian
Rui-Jie Wang
Fu-Hai Wu
Transition Metal Chemistry, 2007, 32 : 332 - 337
[20] Crystal structures of Sr(ClO4)(2)center dot 3H(2)O, Sr(ClO4)(2)center dot 4H(2)O and Sr(ClO4)(2)center dot 9H(2)O
Hennings, Erik
Schmidt, Horst
Voigt, Wolfgang
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2014, 70 : 510 - +

← 1 2 3 4 5 →