Interpenetrating frameworks in the structure of the [(SnMe3)3Re6Se8(CN)6] cluster complex

被引：0
|
作者：
A. Yu. Ledneva
A. V. Virovets
N. G. Naumov
机构：
[1] Russian Academy of Sciences,A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division
来源：
Journal of Structural Chemistry | 2013年 / 54卷
关键词：
rhenium; octahedral cluster; tin;
D O I：
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学科分类号：
摘要：
Single-crystal X-ray diffraction is used to determine the structure of a new compound based on an octahedral cyanide anionic cluster complex of rhenium and a trimethyltin(IV) cation: {(SnMe3)3[Re6Se8(CN)6]} (1). The crystallographic characteristics: space group C2/c, a = 13.9898(14) Å, b =15.334(2) Å, c = 20.761(2) Å, β = 97.75(0)°, V = 4412.91(90) Å3, Z = 4, dx = 3.607 g/cm3, and R = 0.0526. The compound has a framework structure; two porous frameworks with pcu topology interpenetrate each other.
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页码：815 / 819
页数：4
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