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New coordination polymers based on paramagnetic cluster anions [Re6Se8(CN)6]3− and rare earth cations: The synthesis and structure of [{Ln(H2O)3)}{Re6Se8(CN)6}]·3.5H2O

被引：0
|
作者：
M. S. Tarasenko
N. G. Naumov
A. V. Virovets
D. Yu. Naumov
N. V. Kuratieva
Yu. V. Mironov
V. N. Ikorskii
V. E. Fedorov
机构：
[1] Russian Academy of Sciences,Nikolaev Institute of Inorganic Chemistry, Siberian Division
来源：
Journal of Structural Chemistry | 2005年 / 46卷
关键词：
rhenium; octahedral cluster; cyanide complex; rare earth cations; synthesis; crystal structure;
D O I：
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学科分类号：
摘要：
A series of new coordination polymers [{Ln(H2O)3)}{Re6Se8(CN)6}]·3.5H2O based on paramagnetic cluster anions [Re6Se8(CN)6]3− and rare earth metal cations has been prepared. The compounds with Ln = Tb, Dy, Ho, Er, Tm, Yb and Lu are isostructural and crystallize in P21/c space group with the following unit cell parameters: a ≈ 8.8 Å, b ≈ 13.8 Å, c ≈ 23.2 Å, β ≈ 90.5°, V ≈ 2820 Å3, Z = 4. Topologic analysis of the polymeric framework observed in the compounds and its comparison with known mononuclear cyanometallates was performed.
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页码：S137 / S144
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