Hydrothermal Synthesis and Crystal Structure of [{Ag3(Bipy)3(CN)}2Re6Se8(CN)6]

被引：0
|
作者：
Ermolaev, A. V. [1 ]
Mironov, Yu. V. [1 ]
机构：
[1] Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Branch, Novosibirsk, Russia
来源：
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2022年 / 48卷 / 12期
关键词：
hydrothermal synthesis; rhenium; octahedral cluster complex; silver; crystal structure; COORDINATION POLYMERS; CATALYTIC-ACTIVITY; CLUSTER COMPLEXES; LIGAND; FRAMEWORKS; ANIONS; SE;
D O I：
10.1134/S1070328422700038
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A supramolecular ensemble [{Ag-3(Bipy)(3)(CN)}(2)Re6Se8(CN)(6)] (I) is synthesized by the reaction of Cs2.75K1.25[Re6Se8(CN)(4)(OH)(2)]& BULL;H2O with K[Ag(CN)(2)] and 2,2'-bipyridine (Bipy) under the hydrothermal synthesis conditions. The crystal structure consists of polymer layers [{Ag-3(Bipy)(3)(CN)}(2)Re6Se8(CN)(6)]. Inside the layer, each cluster core {Re6Se8}(2+) is linked with six Ag atoms via the CN bridge. Argentophilic interactions Ag center dot center dot center dot Ag (2.9035(6)-2.9697(5) angstrom) complete layer formation. pi-pi-Stacking interactions are observed both inside the layers and between the polymer layers. The synthesized compound is characterized by XRD (CIF file CCDC no. 2170365), IR spectroscopy, and elemental analysis.
引用
收藏
页码：813 / 818
页数：6
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