Anion Selectivities of Dibutyltin Dihalides as Neutral Carriers for Ion-Selective Electrodes

被引：0
|
作者：
Takayo Moriuchi-Kawakami
Hiroshi Aoto
Naotake Takeda
Keiichi Fujimori
Yasuhiko Shibutani
机构：
[1] Faculty of Engineering,Department of Applied Chemistry
[2] Osaka Institute of Technology,undefined
[3] Omiya,undefined
来源：
Analytical Sciences | 2000年 / 16卷
关键词：
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Di-n-butyltin dihalides (Bu2SnY2, Y=Cl, I, OMe) behaved as neutral carriers for anion-selective electrodes. A variety of selectivity patterns have been obtained by using Bu2SnY2 which differ in the electronegative substituents Y on the Sn atom. However, all electrodes containing Bu2SnY2 provided the highest degree of selectivity for the SCN- ion. The interaction of Bu2SnY2 with the SCN- ion was studied in the organic solution by means of 13C NMR spectroscopy. In the case of the addition of NaSCN, a significant increase of the value of 1J(119Sn–13Ca) was observed in the 2.0 M CDCl3 solution of Bu2SnCl2.
引用
收藏
页码：303 / 306
页数：3
相关论文
共 50 条
  • [11] Polyvinyl chloride prasticized ion-selective electrodes based on the neutral carriers for determinations of novocaine
    Nemilova, MY
    Shvedene, NV
    Kochulina, OV
    Pronina, IA
    Pletniov, IV
    VESTNIK MOSKOVSKOGO UNIVERSITETA SERIYA 2 KHIMIYA, 1997, 38 (02): : 99 - 103
  • [12] Organic ammonium ion-selective electrodes using acyclic neutral carriers developed for inorganic cation-selective electrodes
    Katsu, T
    Nishimura, N
    ANALYTICAL SCIENCES, 2000, 16 (05) : 523 - 525
  • [13] Organic Ammonium Ion-Selective Electrodes Using Acyclic Neutral Carriers Developed for Inorganic Cation-Selective Electrodes
    Takashi Katsu
    Nozomi Nishimura
    Analytical Sciences, 2000, 16 : 523 - 525
  • [14] RELATION OF PLASTICIZERS AND IONOPHORE STRUCTURES ON SELECTIVITIES OF LITHIUM ION-SELECTIVE ELECTRODES
    ZHOU, ZN
    XIE, RY
    CHRISTIAN, GD
    ANALYTICAL LETTERS, 1986, 19 (17-18) : 1747 - 1757
  • [15] Ion-selective electrodes:: Polyaniline modification and anion recognition
    Shishkanova, TV
    Sapurina, I
    Stejskal, J
    Král, V
    Volf, R
    ANALYTICA CHIMICA ACTA, 2005, 553 (1-2) : 160 - 168
  • [16] CHARACTERISTICS OF SODIUM ION-SELECTIVE ELECTRODES BASED ON NEUTRAL CARRIERS AND THEIR APPLICATION TO ANALYSIS OF PHYSIOLOGICAL FLUIDS
    SHIBATA, Y
    MARUIZUMI, T
    MIYAGI, H
    NIPPON KAGAKU KAISHI, 1992, (09) : 961 - 967
  • [17] MERCURY(II) ION-SELECTIVE ELECTRODES BASED ON THIA-CROWN LIGAND AS NEUTRAL CARRIERS
    MASUDA, Y
    SEKIDO, E
    BUNSEKI KAGAKU, 1990, 39 (11) : 683 - 687
  • [18] NEUTRAL-CARRIER-BASED ION-SELECTIVE ELECTRODES
    OGGENFUSS, P
    MORF, WE
    OESCH, U
    AMMANN, D
    PRETSCH, E
    SIMON, W
    ANALYTICA CHIMICA ACTA, 1986, 180 : 299 - 311
  • [19] Sodium ion-selective electrodes based on silicone-rubber membranes covalently incorporating neutral carriers
    Tsujimura, Y
    Sunagawa, T
    Yokoyama, A
    Kimura, K
    ANALYST, 1996, 121 (11) : 1705 - 1709
  • [20] Silver ion-selective electrodes using π-coordinate calix[4]arene derivatives as soft neutral carriers
    Kimura, K
    Yajima, S
    Tatsumi, K
    Yokoyama, M
    Oue, M
    ANALYTICAL CHEMISTRY, 2000, 72 (21) : 5290 - 5294
12345