Preparation and crystal structural characterization of Cu(II) complex with piperidine-4-carboxylic acid

被引：0
|
作者：
J. X. Yang
Z. Zhang
Y. P. Tian
J. Y. Wu
Q. L. Liu
A. Usman
S. Chantrapromma
H. K. Fun
机构：
[1] Anhui University,Department of Chemistry
[2] USTC,Department of Chemistry
[3] University Sains Malaysia,X
来源：
Russian Journal of Coordination Chemistry | 2005年 / 31卷
关键词：
Oxygen; Hydrogen; Copper; Reflection; Hydrogen Bond;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Copper(II) complex with piperidine-4-carboxylic acid (HPipe-4), Cu(HPipe-4)4(ClO4)2 (I) was prepared and characterized by IR, X-ray diffraction, and thermal analysis. The crystal is orthorhombic with space group Ccca, Z = 8, a =17.415(3) Å, b =17.399(2) Å, c = 21.426(3) Å. The copper atom has a square surrounding and is coordinated by four carboxylato oxygen atoms in monodentate coordination mode. Full-matrix least-squares refinements gave a final R value of 0.0723 for 22169 reflections. The complex consists of two perpendicularly arranged molecules differing slightly in conformations and shows a three-dimensional polymeric structure formed by hydrogen bonds.
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页码：282 / 285
页数：3
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