Synthesis and crystal structure of bis(4-methylpiperidine-dithiocarbamato-S,S′)-palladium(II)

被引：0

作者：

Saira Shahzadi

Saqib Ali

Amin Badshah

Farkhanda Shaheen

Fiaz Ahmed

Mohammed Fettouhi

机构：

[1] Quaid-i-Azam University,Department of Chemistry

[2] NESCOM,Department of Chemistry

[3] King Fahd University of Petroleum and Minerals,undefined

来源：

Journal of Chemical Crystallography | 2006年 / 36卷

关键词：

Dithiocarbamate; Palladium(II) complex; Crystal structure.;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

The complex bis(4-methylpiperidine-dithiocarbamato-S,S′)-palladium(II) was synthesized by the reaction of 4-methyl-1-piperidine dithiocarbamic acid with palladium(II) chloride. Its structure was determined by X-ray crystal diffraction analysis. It crystallizes in the monoclinic P21/c space group with the crystal cell parameters a=8.6491(8) Å, b=18.7305(16) Å, c=11.9933(10) Å, β=107.074(1)°, V=1857.3(3) Å3 and Z=4. The palladium (II) ion is bonded to four sulfur atoms, belonging to two dithiocarbamate ligands, in a distorted square planar geometry. The X-ray data suggest a pronounced electronic delocalization in the two NCS2 moieties.

引用

页码：567 / 570

页数：3

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