Synthesis and crystal structure of bis(4-methylpiperidine-dithiocarbamato-S,S′)-palladium(II)

被引：0
|
作者：
Saira Shahzadi
Saqib Ali
Amin Badshah
Farkhanda Shaheen
Fiaz Ahmed
Mohammed Fettouhi
机构：
[1] Quaid-i-Azam University,Department of Chemistry
[2] NESCOM,Department of Chemistry
[3] King Fahd University of Petroleum and Minerals,undefined
来源：
Journal of Chemical Crystallography | 2006年 / 36卷
关键词：
Dithiocarbamate; Palladium(II) complex; Crystal structure.;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The complex bis(4-methylpiperidine-dithiocarbamato-S,S′)-palladium(II) was synthesized by the reaction of 4-methyl-1-piperidine dithiocarbamic acid with palladium(II) chloride. Its structure was determined by X-ray crystal diffraction analysis. It crystallizes in the monoclinic P21/c space group with the crystal cell parameters a=8.6491(8) Å, b=18.7305(16) Å, c=11.9933(10) Å, β=107.074(1)°, V=1857.3(3) Å3 and Z=4. The palladium (II) ion is bonded to four sulfur atoms, belonging to two dithiocarbamate ligands, in a distorted square planar geometry. The X-ray data suggest a pronounced electronic delocalization in the two NCS2 moieties.
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页码：567 / 570
页数：3
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