Structural characterization of a novel self-assembly heterohexanuclear complex: [Ni2Ag4(μ-dppm)4(pymt)6](SbF6)2 · 2DMF · H2O

被引：0
|
作者：
Hong-wu Xu
Lin Pin
Jin-xia Li
Zhong-ning Chen
Ji-gui Wu
机构：
[1] ZhongYuan University of Technology,Department of Materials and Chemical Engineering
[2] Fujian Institute of Research on the Structure of Matter,Department of Chemistry
[3] Chinese Academy of Sciences,undefined
[4] Lanzhou University,undefined
来源：
Transition Metal Chemistry | 2007年 / 32卷
关键词：
MeCN; Silver Atom; Dppm; Diphenylphosphino; Diphosphines;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
A novel heterohexanuclear complex [Ni2Ag4(μ-dppm)4(pymt)6](SbF 6)2 · 2DMF · H2O (1), was synthesized by self-assembly with [Ag2(μ-dppm)2(MeCN)2](SbF6) 2 and [Et4N][Ni(pymt)3] (dppm = bis(diphenylphosphino)methane, pymt = pyrimidine-2-thiolate) as components and characterized by IR spectra, elemental analysis, 1H-NMR spectrum, 31P-NMR spectrum and Visible-Ultraviolet spectrum. Structure of the complex was determined by X-ray analysis.
引用
收藏
页码：781 / 783
页数：2
相关论文
共 50 条
  • [31] A novel phenoxy-bridged polynuclear cobalt complex. Synthesis and structural characterization of [Co7Na2(1,2-OSC6H4)(8)(DMF)(12)]center dot 2DMF center dot H2O
    Hong, MC
    Jiang, FL
    Huang, XY
    Su, WP
    Li, WJ
    Cao, R
    Liu, HQ
    INORGANICA CHIMICA ACTA, 1997, 256 (01) : 137 - 141
  • [32] Synthesis, Structure and Characterization of a New Transition Metal Complex: [Co0.5Ni0.5(C6H12N4)2(H2O)4]2 [Co0.5Ni0.5(H2O)6]2[SO4]4•13H2O
    Li, Dengpeng
    Xu, Zhihuang
    Ye, Liwang
    Cao, Tengfei
    Zhuang, Xinxin
    JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2022, 52 (03) : 337 - 344
  • [33] Synthesis, Structure and Characterization of a New Transition Metal Complex: [Co0.5Ni0.5(C6H12N4)2(H2O)4]2 [Co0.5Ni0.5(H2O)6]2[SO4]4·13H2O
    Dengpeng Li
    Zhihuang Xu
    Liwang Ye
    Tengfei Cao
    Xinxin Zhuang
    Journal of Chemical Crystallography, 2022, 52 : 337 - 344
  • [34] Temperature dependence of the crystal structure and luminescence properties of [Pt{4′-(o-ClC6H4)trpy}Cl]SbF6 (trpy=2,2′:6′,2"-terpyridine)
    Field, JS
    Gertenbach, JA
    Haines, RJ
    Ledwaba, LP
    Mashapa, NT
    McMillin, DR
    Munro, OQ
    Summerton, GC
    DALTON TRANSACTIONS, 2003, (06) : 1176 - 1180
  • [35] [(C6H10)(NH3)2][Ni(H2O)4C6H2(COO)4]•4H2O -: A coordination polymer with the chain-like polyanion {Ni(H2O)4[C6H2(COO)4]2-}n
    Koeferstein, Roberto
    Robl, Christian
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2007, 633 (09): : 1323 - 1325
  • [36] Synthesis and luminescence properties of [Pt{4-(o-MeC6H4)-pzbipy)CI]SbF6 [pzbipy=6-2"-pyrazinyl)-2,2′-bipyridine]
    Field, John S.
    Gertenbach, Jan-Andre
    Haines, Raymond J.
    Munro, Orde Q.
    McMillin, David R.
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 2007, 62 (03): : 447 - 452
  • [37] From molecular to two-dimensional Anderson polyoxomolybdate:: Synthesis, crystal structure, and thermal behavior of [{Ni(H2O)4}2{Ni(OH)6Mo6O18}]•4H2O and [Ni(H2O)6][Ag2{Ni(OH)6Mo6O18}]•8H2O
    Liu, Feng-Xian
    Marchal-Roch, Catherine
    Dambournet, Damien
    Acker, Aloies
    Marrot, Jerome
    Secheresse, Francis
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2008, (13) : 2191 - 2198
  • [38] Synthesis and luminescence properties of [Pt{4-(o-MeC6H 4)-pzbipy}Cl]SbF6 [pzbipy = 6-2″-pyrazinyl-2, 2′-bipyridine]
    Field, John S.
    Gertenbach, Jan-André
    Haines, Raymond J.
    Munro, Orde Q.
    McMillin, David R.
    Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences, 2007, 62 (03): : 447 - 452
  • [39] Synthesis and characterization of the gold(I) tris(ethylene) complex [AU(C2H4)3][SbF6]
    Dias, H. V. Rasika
    Fianchini, Mauro
    Cundari, Thomas R.
    Campana, Charles F.
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (03) : 556 - 559
  • [40] HALOCARBON BINDING IN [IR(COD)(ETA-2-ORTHO-BRC6H4PPH2)]SBF6
    BURK, MJ
    CRABTREE, RH
    HOLT, EM
    ORGANOMETALLICS, 1984, 3 (04) : 638 - 640
12345