Structural characterization of a novel self-assembly heterohexanuclear complex: [Ni2Ag4(μ-dppm)4(pymt)6](SbF6)2 · 2DMF · H2O

被引：0
|
作者：
Hong-wu Xu
Lin Pin
Jin-xia Li
Zhong-ning Chen
Ji-gui Wu
机构：
[1] ZhongYuan University of Technology,Department of Materials and Chemical Engineering
[2] Fujian Institute of Research on the Structure of Matter,Department of Chemistry
[3] Chinese Academy of Sciences,undefined
[4] Lanzhou University,undefined
来源：
Transition Metal Chemistry | 2007年 / 32卷
关键词：
MeCN; Silver Atom; Dppm; Diphenylphosphino; Diphosphines;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
A novel heterohexanuclear complex [Ni2Ag4(μ-dppm)4(pymt)6](SbF 6)2 · 2DMF · H2O (1), was synthesized by self-assembly with [Ag2(μ-dppm)2(MeCN)2](SbF6) 2 and [Et4N][Ni(pymt)3] (dppm = bis(diphenylphosphino)methane, pymt = pyrimidine-2-thiolate) as components and characterized by IR spectra, elemental analysis, 1H-NMR spectrum, 31P-NMR spectrum and Visible-Ultraviolet spectrum. Structure of the complex was determined by X-ray analysis.
引用
收藏
页码：781 / 783
页数：2
相关论文
共 50 条
  • [21] Synthesis, Structure and Characterization of a New Complex: [Mn(C6H12N4)2(H2O)4][Mn(H2O)6][SO4]2•t6H2O
    Li Deng-Peng
    Xu Zhi-Huang
    Ye Li-Wang
    Cao Teng-Fei
    Zhuang Xin-Xin
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2021, 40 (09) : 1169 - 1176
  • [22] Self-assembly and crystal structure of a novel inorganic-organic hybrid coordination polymer:: [(C10H16N)2(Pb2I6)•2DMF•H2O]n
    Li, HH
    Chen, ZR
    Huang, CC
    Lian, ZX
    Chen, JH
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2004, 20 (06) : 703 - 706
  • [23] Synthesis and crystal structure of the complex [Mg(H2O)2(dmf@CB[6])(bdc)]·DMF·4H2O and the inclusion compound [dmf@CB[6]]·8H2O
    E. A. Kovalenko
    D. G. Samsonenko
    D. Yu. Naumov
    V. P. Fedin
    Russian Chemical Bulletin, 2014, 63 : 64 - 67
  • [24] Synthesis and crystal structure of the complex [Mg(H2O)2(dmf@CB[6])(bdc)]•DMF•4H2O and the inclusion compound [dmf@CB[6]]•8H2O
    Kovalenko, E. A.
    Samsonenko, D. G.
    Naumov, D. Yu.
    Fedin, V. P.
    RUSSIAN CHEMICAL BULLETIN, 2014, 63 (01) : 64 - 67
  • [25] A dinuclear cyanide-bridged complex, [(DMF)4(H2O)3LuCo(CN)6]·H2O
    Brian P. Cunningham
    Jason A. Kautz
    Journal of Chemical Crystallography, 2000, 30 : 671 - 675
  • [26] A dinuclear cyanide-bridged complex, [(DMF)4(H2O)3LuCo(CN)6]•H2O
    Cunningham, BP
    Kautz, JA
    JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2000, 30 (10) : 671 - 675
  • [27] Synthesis and structural characterization of Mo2(μ-SC6H4-Cl-p)2(μ-dppm)(CO)6 and [(dppm)(CO)2Mo(μ-SC6H4-Cl-p)2Mo(O)]2(μ-SC6H4-Cl-p)2(μ-O) and electrochemical property of Mo2(μ-SC6H4-Cl-p)2(μ-dppm)(CO)6
    Pan, GH
    Zhuang, BT
    He, LJ
    Chen, JT
    Lu, JX
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1999, 580 (02) : 313 - 319
  • [28] Synthesis, crystal structures, and properties of [Ca(H2O)2(Dmf@CB[6])(Bdc)] • DMF • 4H2O and [Ca(H2O)3(Dmf@CB[6])]Cl2 • 2H2O
    Kovalenko, E. A.
    Palatkina, M. Yu
    Samsonenko, D. G.
    Fedin, V. P.
    RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2012, 38 (06) : 379 - 385
  • [29] Synthesis, crystal structures, and properties of [Ca(H2O)2(Dmf@CB[6])(Bdc)] · DMF · 4H2O and [Ca(H2O)3(Dmf@CB[6])]Cl2 · 2H2O
    E. A. Kovalenko
    M. Yu. Palatkina
    D. G. Samsonenko
    V. P. Fedin
    Russian Journal of Coordination Chemistry, 2012, 38 : 379 - 385
  • [30] Synthesis and Crystal Structure of a Heterotetranuclear Complex: [Et4N]2[Pd2Ag2(-dppm)2(i-mnt)4]•2DMF•MeCN
    Xu, Hong-Wu
    Li, Ying-Hua
    Zhang, Liu-Xue
    SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2013, 43 (10) : 1552 - 1555
12345