Crystal Structure of the Octahedral Rhenium Cluster Complex (Bu4N)4[Re6S8(OC6H4-p-NO2)6]

被引：0
|
作者：
S. Nagashima
S. Kawada
H. Kobayashi
机构：
[1] Saitama University,Graduate School of Science and Engineering
来源：
Journal of Structural Chemistry | 2019年 / 60卷
关键词：
rhenium; octahedral chalcogenide cluster; -nitrophenolate; crystal structure;
D O I：
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摘要：
A cluster complex with the composition (Bu4N)4[Re6S8(CC6H4-p-NC2)6] having terminal phenoxide ligands is obtained by the reaction of (Bu4N)4[Re6S8Cl6] with silver p-nitrophenolate. The compound crystallizes in the orthorhombic space group Pccn with the following unit cell parameters: a = 19.507(2) Å, b = 31.645(3) Å, c = 19.237(2) Å, V = 19.237(2) Å3, Z = 4, dcalc = 1.774 g/cm3.
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页码：299 / 301
页数：2
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