A new hexanuclear rhenium cluster complex with six terminal acetate ligands: Synthesis, structure, and properties of K4[Re6S8(CH3COO)6]•8H2O

被引：34
|
作者：
Brylev, Konstantin A. [1 ]
Mironov, Yuri V. [1 ]
Fedorov, Vladimir E. [1 ]
Kim, Sung-Jin [2 ]
Pietzsch, Hans-Juergen [3 ]
Stephan, Holger [3 ]
Ito, Akitaka [4 ]
Kitamura, Noboru [4 ]
机构：
[1] Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Branch, Novosibirsk 630090, Russia
[2] Ewha Womans Univ, Dept Chem & Nano Sci, Seoul 120750, South Korea
[3] Forschungszentrum Dresden Rossendorf, Inst Radiopharm, D-01314 Dresden, Germany
[4] Hokkaido Univ, Dept Chem, Grad Sch Sci, Sapporo, Hokkaido 0600810, Japan
来源：
INORGANICA CHIMICA ACTA | 2010年 / 363卷 / 11期
基金：
日本学术振兴会; 俄罗斯基础研究基金会;
关键词：
Synthesis; Cluster compounds; Rhenium; Carboxylate ligands; Luminescence; CRYSTAL-STRUCTURE; HEXARHENIUM(III) CLUSTERS; ACETIC-ACID; ORGANIC-LIGANDS; CORE; SE; MOLYBDENUM; SUBSTITUTION; LUMINESCENT; TEMPERATURE;
D O I：
10.1016/j.ica.2010.04.042
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A room-temperature reaction between [Re6S8(OH)(6)](4) and acetic acid in an aqueous solution resulted in the substitution of all terminal hydroxo groups by acetate ligands, affording a new hexanuclear anionic rhenium cluster complex [Re6S8(CH3COO)(6)](4). The complex was isolated as a potassium salt with the composition of K-4[Re6S8(CH3COO)(6)]center dot 8H(2)O (1) and characterized by X-ray single- crystal diffraction and elemental analyses, IR, H-1 NMR, UV-Vis, and luminescence spectroscopies. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码：2686 / 2691
页数：6
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