Two 3D Supramolecular Coordination Polymers Constructed from Aromatic Carboxylic Acids and Flexible Bis(thiabendazole) Ligands

被引：0
|
作者：
Xiao-Xue Zhao
Zeng-Chuan Hao
Suo-Xia Hou
Guang Hua Cui
机构：
[1] North China University of Science and Technology,College of Chemical Engineering, Hebei Key Laboratory for Environment Photocatalytic and Electrocatalytic Materials
来源：
Journal of Inorganic and Organometallic Polymers and Materials | 2017年 / 27卷
关键词：
Bis(thiabendazole); Cobalt(II); Coordination polymer; Crystal structure; Zinc(II);
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Two coordination polymers (CPs), [Zn(L1)(H2bta)] (1) and [Co(L2)(ndc)]·0.75H2O (2), (L1 = 1,6-(thiabendazole)hexane), L2 = 1,3-(thiabendazole)propane, H4bta = 1,2,4,5-benzenetetracarboxylic acid, H2ndc = 2,6-naphthalenedicarboxylic acid) have been hydrothermally synthesized and characterized. Single crystal X-ray diffraction analyses reveal that CP 1 and CP 2 feature 1D infinite zigzag and “Ω”-like chains, and further extend into 3D supramolecular framework by O–H⋯O and C–H⋯O hydrogen bonding interactions, respectively. Furthermore, the luminescence properties, thermal stability, and catalytic degradation of methyl orange in a Fenton-like process are also investigated in detail.
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页码：934 / 940
页数：6
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