Two Interpenetrated Dia-type Coordination Polymers Constructed from Mixed Dicarboxylate and Bis(imidazol)-based Ligands

被引：0
|
作者：
覃业燕 [1 ,2 ]
杨锦霞 [1 ]
张鑫 [1 ]
叶闰平 [1 ]
姚元根 [1 ]
机构：
[1] State Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences
[2] University of Chinese Academy of Sciences
来源：
Chinese Journal of Structural Chemistry | 2015年 / 34卷 / 11期
关键词：
cadmium; flexible ligand; diamondoid network; fluorescent property;
D O I：
10.14102/j.cnki.0254-5861.2011-0740
中图分类号：
O634 [元素有机聚合物];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Two novel interpenetrating diamond frameworks,namely [Cd(mal)(bix)]n(1) and {[Zn(sub)(bib)]n·H2O}n(2)(H2mal=maleic acid,H2 sub=suberic acid,bix=1,4-bis(imidazol-1-ylmethyl)-benzene,bib=1,4-bis(N-imidazolyl)butane) were hydrothermally synthesized and characterized by elemental analysis,infrared spectra(IR),and single-crystal X-ray diffraction.Single-crystal X-ray diffraction analysis reveals that compound 1 crystallizes in the orthorhombic system with space group Pnma and features a 3-fold interpenetrating diamond framework.Compound 2 exhibits a 4-fold interpenetrating diamond network.The luminescent properties of these two compounds have also been investigated in detail.
引用
收藏
页码：1717 / 1722
页数：6
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