Non-steady-state photo-EMF in nanostructured GaN and polypyrrole within porous matrices

We report an experimental investigation of the non-steady-state photoelectromotive force in nanostructured GaN within porous glass and polypyrrole within chrysotile asbestos. The samples are illuminated by an oscillating interference pattern created by two coherent light beams and the alternating current is detected as a response of the material. Dependences of the signal amplitude versus temporal and spatial frequencies, light intensity, and temperature are studied for two wavelengths λ=442 and 532 nm. The conductivity of the GaN composite is measured: σ=(1.1–1.6)×10−10 Ω−1 cm−1 (λ=442 nm, I0=0.045–0.19 W/cm2, T=293 K) and σ=(3.5–4.6)×10−10 Ω−1 cm−1 (λ=532 nm, I0=2.3 W/cm2, T=249–388 K). The diffusion length of photocarriers in polypyrrole nanowires is also estimated: LD=0.18 μm.