The standard enthalpy of formation of fullerene chloride C60Cl30

被引：0
|
作者：
T. S. Papina
V. A. Luk’yanova
S. I. Troyanov
N. V. Chelovskaya
A. G. Buyanovskaya
L. N. Sidorov
机构：
[1] Moscow State University,Faculty of Chemistry
[2] Russian Academy of Sciences,Nesmeyanov Institute of Organoelement Compounds
来源：
Russian Journal of Physical Chemistry A | 2007年 / 81卷
关键词：
Fullerene; Benzoic Acid; Bond Energy; Standard Enthalpy; Free Chlorine;
D O I：
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中图分类号：
学科分类号：
摘要：
A rotating-bomb calorimeter was used to measure the energy of combustion of crystalline fullerene chloride C60Cl30 · 0.09Cl2, ΔcU° = (−24474 ± 135 kJ/mol). The result was used to calculate the standard enthalpy of formation, ΔfH° (C60Cl30, cr) = 135 ± 135 kJ/mol, and the C-Cl bond energy, 195 ± 5 kJ/mol. The C-X (X = F, F, Cl, and Br) bond energies in fullerene C60 derivatives and other organic compounds are compared.
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页码：159 / 163
页数：4
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