The reaction of [Ru(bpy)2(NO)Cl]2+ and [Fe(CN)5NO]2− with benzylamine: coordinated nitrosyl as an oxidizing agent

被引：0
|
作者：
Fabio Doctorovich
María Granara
Florencia Di Salvo
机构：
[1] Universidad de Buenos Aires,Departamento de Química Inorgánica, Analítica y Química Física/INQUIMAE, Facultad de Ciencias Exactas y Naturales
来源：
Transition Metal Chemistry | 2001年 / 26卷
关键词：
Oxidation; Oxygen; Physical Chemistry; Inorganic Chemistry; Benzyl;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
[Fe(CN)5NO]2−, (1) and [Ru(bpy)2(NO)Cl]2+, (2) react with PhCH2NH2 to produce mainly N-benzylphenyl-methanimine and PhCN as oxidation products. (PhCH2)2NH, PhCH2Cl and PhCH2OH are formed as diazotization products. Products derived from the benzyl radical (such as PhMe), are also formed. Since oxidation products are generated even in the absence of oxygen, a mechanism in which the nitrosyl ligand acts as an oxidant is proposed.
引用
收藏
页码：505 / 509
页数：4
相关论文
共 50 条
  • [1] The reaction of [Ru(bpy)2(NO)Cl]2+ and [Fe(CN)5NO]2- with benzylamine:: coordinated nitrosyl as an oxidizing agent
    Doctorovich, F
    Granara, M
    Di Salvo, F
    TRANSITION METAL CHEMISTRY, 2001, 26 (4-5) : 505 - 509
  • [2] Oxidation of coordinated ammonia to nitrosyl in the reaction of aqueous chlorine with cis-[Ru(bpy)(2)(NH3)(2)](2+)
    Assefa, Z
    Stanbury, DM
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (03) : 521 - 530
  • [3] Electronic Structure and Spectroscopy of [Ru(tpy)2]2+, [Ru(tpy)(bpy)(H2O)]2+, and [Ru(tpy)(bpy)(Cl)]+
    Jakubikova, Elena
    Chen, Weizhong
    Dattelbaum, Dana M.
    Rein, Francisca N.
    Rocha, Reginaldo C.
    Martin, Richard L.
    Batista, Enrique R.
    INORGANIC CHEMISTRY, 2009, 48 (22) : 10720 - 10725
  • [4] TEMPERATURE-DEPENDENCE OF THE RU(BPY)2(CN)2 AND RU(BPY)2(I-BIQ)2+ LUMINESCENCE
    BARIGELLETTI, F
    JURIS, A
    BALZANI, V
    BELSER, P
    VONZELEWSKY, A
    JOURNAL OF PHYSICAL CHEMISTRY, 1987, 91 (05): : 1095 - 1098
  • [5] Reaction pathways of 2,2,2-trifluoroethylamine and n-butylamine with [Ru(bpy)2(NO)Cl]2+
    Di Salvo, F
    Crespo, A
    Estrin, DA
    Doctorovich, F
    TETRAHEDRON, 2002, 58 (21) : 4237 - 4244
  • [6] Metastable states of ruthenium (II) nitrosyl complexes and comparison with [Fe(CN)5NO]2-
    Gorelsky, SI
    Lever, ABP
    INTERNATIONAL JOURNAL OF QUANTUM CHEMISTRY, 2000, 80 (4-5) : 636 - 645
  • [7] ISOLATION OF INTERMEDIATES IN THE WATER GAS SHIFT REACTIONS CATALYZED BY [RU(BPY)2(CO)CL]+ AND [RU(BPY)2(CO)2]2+
    ISHIDA, H
    TANAKA, K
    MORIMOTO, M
    TANAKA, T
    ORGANOMETALLICS, 1986, 5 (04) : 724 - 730
  • [8] Photosubstitution Reaction of cis-[Ru(bpy)2(CH3CN)2]2+ and cis-[Ru(bpy)2(NH3)2]2+ in Aqueous Solution via Monoaqua Intermediate
    Kayanuma, Megumi
    Shoji, Mitsuo
    Shigeta, Yasuteru
    JOURNAL OF PHYSICAL CHEMISTRY A, 2019, 123 (13): : 2497 - 2502
  • [9] Electronic absorption spectroscopy of [Ru(phen)2(bpy)]2+, [Ru(phen)2(dmbp)]2+, [Ru(tpy)(phen)(CH3CN)]2+ and [Ru(tpy)(dmp)(CH3CN)]2+ A theoretical study
    Bossert, Julien
    Daniel, Chantal
    COORDINATION CHEMISTRY REVIEWS, 2008, 252 (23-24) : 2493 - 2503
  • [10] STRUCTURE OF REACTION PRODUCT OF FE[(CN)5NO]2- WITH S2- IONS
    BARAN, EJ
    MULLER, A
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1969, 8 (11) : 890 - &
12345