The reaction of [Ru(bpy)2(NO)Cl]2+ and [Fe(CN)5NO]2− with benzylamine: coordinated nitrosyl as an oxidizing agent

被引：0
|
作者：
Fabio Doctorovich
María Granara
Florencia Di Salvo
机构：
[1] Universidad de Buenos Aires,Departamento de Química Inorgánica, Analítica y Química Física/INQUIMAE, Facultad de Ciencias Exactas y Naturales
来源：
Transition Metal Chemistry | 2001年 / 26卷
关键词：
Oxidation; Oxygen; Physical Chemistry; Inorganic Chemistry; Benzyl;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
[Fe(CN)5NO]2−, (1) and [Ru(bpy)2(NO)Cl]2+, (2) react with PhCH2NH2 to produce mainly N-benzylphenyl-methanimine and PhCN as oxidation products. (PhCH2)2NH, PhCH2Cl and PhCH2OH are formed as diazotization products. Products derived from the benzyl radical (such as PhMe), are also formed. Since oxidation products are generated even in the absence of oxygen, a mechanism in which the nitrosyl ligand acts as an oxidant is proposed.
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页码：505 / 509
页数：4
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