Reaction pathways of 2,2,2-trifluoroethylamine and n-butylamine with [Ru(bpy)2(NO)Cl]2+

被引：7
|
作者：
Di Salvo, F [1 ]
Crespo, A [1 ]
Estrin, DA [1 ]
Doctorovich, F [1 ]
机构：
[1] Univ Buenos Aires, Fac Ciencias Exactas & Nat, Dept Quim Inorgan Analit & Quim Fis, INQUIMAE, RA-1428 Buenos Aires, DF, Argentina
来源：
TETRAHEDRON | 2002年 / 58卷 / 21期
关键词：
n-butylamine; density functional theory; electron transfer; 2,2,2-trifluoroethylamine; nitrosyl; ruthenium; complex;
D O I：
10.1016/S0040-4020(02)00382-4
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The reaction of [Ru(bpy)(2)(NO)Cl](2+) with 2,2,2-trifluoroethylamine produced [Ru(bpy)(2)(NO)Cl](+) by electron transfer and a number of organic compounds formed via nucleophilic substitution of the intermediate 2,2,2-trifluoroethyldiazonium ion (free or coordinated). Density functional theory computed results suggest that stabilization of the trifluoroethyldiazonium ion by complexation is much larger than the one corresponding to the butyl ion, in agreement with the fact that no rearrangement products derived from CF3CH2+ were observed. (C) 2002 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：4237 / 4244
页数：8
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