Reaction pathways of 2,2,2-trifluoroethylamine and n-butylamine with [Ru(bpy)2(NO)Cl]2+

被引：7
|
作者：
Di Salvo, F [1 ]
Crespo, A [1 ]
Estrin, DA [1 ]
Doctorovich, F [1 ]
机构：
[1] Univ Buenos Aires, Fac Ciencias Exactas & Nat, Dept Quim Inorgan Analit & Quim Fis, INQUIMAE, RA-1428 Buenos Aires, DF, Argentina
来源：
TETRAHEDRON | 2002年 / 58卷 / 21期
关键词：
n-butylamine; density functional theory; electron transfer; 2,2,2-trifluoroethylamine; nitrosyl; ruthenium; complex;
D O I：
10.1016/S0040-4020(02)00382-4
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The reaction of [Ru(bpy)(2)(NO)Cl](2+) with 2,2,2-trifluoroethylamine produced [Ru(bpy)(2)(NO)Cl](+) by electron transfer and a number of organic compounds formed via nucleophilic substitution of the intermediate 2,2,2-trifluoroethyldiazonium ion (free or coordinated). Density functional theory computed results suggest that stabilization of the trifluoroethyldiazonium ion by complexation is much larger than the one corresponding to the butyl ion, in agreement with the fact that no rearrangement products derived from CF3CH2+ were observed. (C) 2002 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：4237 / 4244
页数：8
相关论文
共 50 条
  • [21] Synthesis, DNA-binding and photocleavage studies of ruthenium complexes [Ru(bpy)2(mitatp)]2+ and [Ru(bpy)2(nitatp)]2+
    Yu, Hui-Juan
    Huang, Shu-Mei
    Li, Lv-Ying
    Jia, Hai-Na
    Chao, Hui
    Mao, Zong-Wan
    Liu, Jian-Zhong
    Ji, Liang-Nian
    JOURNAL OF INORGANIC BIOCHEMISTRY, 2009, 103 (06) : 881 - 890
  • [22] Synthesis, characterization and DNA binding studies of ruthenium(II) complexes: [Ru(bpy)2(dtmi)]2+ and [Ru(bpy)2(dtni)]2+
    Yun-Jun Liu
    Xin Yu Wei
    Wen-Jie Mei
    Li-Xin He
    Transition Metal Chemistry, 2007, 32 : 762 - 768
  • [23] The reaction of [Ru(bpy)2(NO)Cl]2+ and [Fe(CN)5NO]2- with benzylamine:: coordinated nitrosyl as an oxidizing agent
    Doctorovich, F
    Granara, M
    Di Salvo, F
    TRANSITION METAL CHEMISTRY, 2001, 26 (4-5) : 505 - 509
  • [24] Synthesis, characterization and DNA binding studies of ruthenium(II) complexes:: [Ru(bpy)2(dtmi)]2+ and [Ru(bpy)2(dtni)]2+
    Liu, Yun-Jun
    Wei, Xin Yu
    Mei, Wen-Jie
    He, Li-Xin
    TRANSITION METAL CHEMISTRY, 2007, 32 (06) : 762 - 768
  • [25] Aqueous in situ derivatization of carboxylic acids by an ionic carbodiimide and 2,2,2-trifluoroethylamine for electron-capture detection
    Ford, Quincy LaRon
    Burns, Justina Marie
    Ferry, John Lee
    JOURNAL OF CHROMATOGRAPHY A, 2007, 1145 (1-2) : 241 - 245
  • [26] RU(BPY)2(2+) AND OS(BPY)2(2+) COMPLEXES OF LARGE POLYAZA CAVITY-SHAPED LIGANDS
    THUMMEL, RP
    WILLIAMSON, D
    HERY, C
    INORGANIC CHEMISTRY, 1993, 32 (09) : 1587 - 1596
  • [27] REACTION BETWEEN AZIDE ION AND (RU(BIPY)2(NO)CL]2+
    MILLER, FJ
    MEYER, TJ
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1971, 93 (05) : 1294 - &
  • [28] ELECTROCHEMICAL CO2 REDUCTION CATALYZED BY [RU(BPY)2(CO)2]2+ AND [RU(BPY)2(CO)CL]+ - THE EFFECT OF PH ON THE FORMATION OF CO AND HCOO-
    ISHIDA, H
    TANAKA, K
    TANAKA, T
    ORGANOMETALLICS, 1987, 6 (01) : 181 - 186
  • [29] SIMULTANEOUS PHOTOOXIDATION OF [RU(BPY)(2)CL-2] AND PHOTOREDUCTION OF [RU(BPY)(2)CL-2](+) IN SEVERAL SOLVENT SYSTEMS
    TONG, CC
    WINKELMAN, M
    JAIN, A
    JENSEN, SP
    HOGGARD, PE
    INORGANICA CHIMICA ACTA, 1994, 226 (1-2) : 247 - 250
  • [30] TEMPERATURE-DEPENDENCE OF THE RU(BPY)2(CN)2 AND RU(BPY)2(I-BIQ)2+ LUMINESCENCE
    BARIGELLETTI, F
    JURIS, A
    BALZANI, V
    BELSER, P
    VONZELEWSKY, A
    JOURNAL OF PHYSICAL CHEMISTRY, 1987, 91 (05): : 1095 - 1098
12345