Solid-phase thermal decomposition of polynuclear nickel(II) and cobalt(II) complexes

被引：0
|
作者：
Zh. V. Dobrokhotova
I. G. Fomina
M. A. Kiskin
A. A. Sidorov
V. M. Novotortsev
I. L. Eremenko
机构：
[1] Russian Academy of Sciences,N. S. Kurnakov Institute of General and Inorganic Chemistry
来源：
Russian Chemical Bulletin | 2006年 / 55卷
关键词：
polynuclear complexes; cobalt and nickel complexes; carboxylate ligands; thermal decomposition;
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学科分类号：
摘要：
Solid-phase thermal decomposition of polynuclear NiII and CoII pivalate complexes was studied by differential scanning calorimetry and thermogravimetry. The decomposition of the polynuclear (from bi-to hexanuclear) CoII carboxylate complexes is accompanied by aggregation to form a volatile octanuclear complex. Thermolysis of the polynuclear NiII carboxylates results in their destructure, and the phase composition of the decomposition products is determined by the nature of coordinated ligands.
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页码：256 / 266
页数：10
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