Solid-phase thermal decomposition of polynuclear nickel(II) and cobalt(II) complexes

被引：15

作者：

Dobrokhotova, Zh. V. ^{[1
]}

Fomina, I. G. ^{[1
]}

Kiskin, M. A. ^{[1
]}

Sidorov, A. A. ^{[1
]}

Novotortsev, V. M. ^{[1
]}

Eremenko, I. L. ^{[1
]}

机构：

[1] Russian Acad Sci, NS Kurnakov Gen & Inorgan Chem Inst, Moscow 119991, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 2006年 / 55卷 / 02期

基金：

俄罗斯基础研究基金会;

关键词：

polynuclear complexes; cobalt and nickel complexes; carboxylate ligands; thermal decomposition;

D O I：

10.1007/s11172-006-0246-7

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Solid-phase thermal decomposition of polynuclear Ni-II and Co-II pivalate complexes was studied by differential scanning calorimetry and thermogravimetry. The decomposition of the polynuclear (from bi- to hexanuclear) Co-II carboxylate complexes is accompanied by aggregation to form a volatile octanuclear complex. Thermolysis of the polynuclear Ni-II carboxylates results in their destructure, and the phase composition of the decomposition products is determined by the nature of coordinated ligands.

引用

页码：256 / 266

页数：11

共 50 条

[1] Solid-phase thermal decomposition of polynuclear nickel(II) and cobalt(II) complexes
Zh. V. Dobrokhotova
I. G. Fomina
M. A. Kiskin
A. A. Sidorov
V. M. Novotortsev
I. L. Eremenko
[J]. Russian Chemical Bulletin, 2006, 55 : 256 - 266
[2] THERMAL STUDIES OF COBALT(II) COMPLEXES OF HYDRAZINE IN THE SOLID-PHASE
BANERJEE, B
BISWAS, PK
CHAUDHURI, NR
[J]. THERMOCHIMICA ACTA, 1984, 76 (1-2) : 47 - 62
[3] THERMAL INVESTIGATION OF DIAMINE COMPLEXES OF NICKEL(II) IN THE SOLID-PHASE
MITRA, S
DE, G
CHAUDHURI, NR
[J]. THERMOCHIMICA ACTA, 1983, 66 (1-3) : 187 - 195
[4] Anaerobic solid-phase thermal configurational transformations of cobalt(II) complexes
ElBehairy, M
[J]. BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1996, 69 (05) : 1247 - 1254
[5] 36-Nuclear anionic cobalt(II) and nickel(II) complexes in solid-phase insertion reactions
Vologzhaninaa, A. V.
Zorina-Tikhonova, E. N.
Matyukhina, A. K.
Sidorov, A. A.
Dorovatovskii, P. V.
Eremenko, I. L.
[J]. RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2017, 43 (12) : 801 - 806
[6] 36-Nuclear anionic cobalt(II) and nickel(II) complexes in solid-phase insertion reactions
A. V. Vologzhanina
E. N. Zorina-Tikhonova
A. K. Matyukhina
A. A. Sidorov
P. V. Dorovatovskii
I. L. Eremenko
[J]. Russian Journal of Coordination Chemistry, 2017, 43 : 801 - 806
[7] THERMAL-DECOMPOSITION KINETICS OF SALICYLIDENEAMINOFLUORENE COMPLEXES OF COBALT(II) AND NICKEL(II)
INDIRA, V
PARAMESWARAN, G
[J]. THERMOCHIMICA ACTA, 1986, 101 : 145 - 154
[8] Thermal decomposition of phenanthroline complexes of cobalt(II) and nickel(II) chlorides in inert atmosphere
Kryatova, OP
Mashkin, OA
Kalibabchuk, VA
[J]. ZHURNAL NEORGANICHESKOI KHIMII, 1995, 40 (12): : 1973 - 1976
[9] Thermal decomposition kinetics of nickel(II) and cobalt(II) azo barbituric acid complexes
Li, Xiaoyi
Wu, Yiqun
Gu, Donghong
Gan, Fuxi
[J]. THERMOCHIMICA ACTA, 2009, 493 (1-2) : 85 - 89
[10] THERMAL-DECOMPOSITION OF THIOSALICYLAMIDE COMPLEXES OF COBALT(II), NICKEL(II) AND MOLYBDENUM(VI)
WESOLOWSKI, M
LEWICKA, M
[J]. ROCZNIKI CHEMII, 1976, 50 (09): : 1607 - 1612

← 1 2 3 4 5 →