Solid-phase thermal decomposition of polynuclear nickel(II) and cobalt(II) complexes

被引：15

作者：

Dobrokhotova, Zh. V. ^{[1
]}

Fomina, I. G. ^{[1
]}

Kiskin, M. A. ^{[1
]}

Sidorov, A. A. ^{[1
]}

Novotortsev, V. M. ^{[1
]}

Eremenko, I. L. ^{[1
]}

机构：

[1] Russian Acad Sci, NS Kurnakov Gen & Inorgan Chem Inst, Moscow 119991, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 2006年 / 55卷 / 02期

基金：

俄罗斯基础研究基金会;

关键词：

polynuclear complexes; cobalt and nickel complexes; carboxylate ligands; thermal decomposition;

D O I：

10.1007/s11172-006-0246-7

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Solid-phase thermal decomposition of polynuclear Ni-II and Co-II pivalate complexes was studied by differential scanning calorimetry and thermogravimetry. The decomposition of the polynuclear (from bi- to hexanuclear) Co-II carboxylate complexes is accompanied by aggregation to form a volatile octanuclear complex. Thermolysis of the polynuclear Ni-II carboxylates results in their destructure, and the phase composition of the decomposition products is determined by the nature of coordinated ligands.

引用

页码：256 / 266

页数：11

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