Solid-phase thermal decomposition of polynuclear nickel(II) and cobalt(II) complexes

被引：0

作者：

Zh. V. Dobrokhotova

I. G. Fomina

M. A. Kiskin

A. A. Sidorov

V. M. Novotortsev

I. L. Eremenko

机构：

[1] Russian Academy of Sciences,N. S. Kurnakov Institute of General and Inorganic Chemistry

来源：

Russian Chemical Bulletin | 2006年 / 55卷

关键词：

polynuclear complexes; cobalt and nickel complexes; carboxylate ligands; thermal decomposition;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

Solid-phase thermal decomposition of polynuclear NiII and CoII pivalate complexes was studied by differential scanning calorimetry and thermogravimetry. The decomposition of the polynuclear (from bi-to hexanuclear) CoII carboxylate complexes is accompanied by aggregation to form a volatile octanuclear complex. Thermolysis of the polynuclear NiII carboxylates results in their destructure, and the phase composition of the decomposition products is determined by the nature of coordinated ligands.

引用

页码：256 / 266

页数：10

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