Actinide molecular ion formation in collision/reaction cell of triple quadrupole ICP-MS/MS and its application to quantitative actinide analysis

被引：0
|
作者：
T. Suzuki
T. Yamamura
C. Abe
K. Konashi
Y. Shikamori
机构：
[1] Nagaoka University of Technology,Department of Nuclear System Safety Engineering
[2] Institute for Materials Research,Laboratory of Alpha
[3] Tohoku University,Ray Emitters
[4] Kyoto University,Institute for Integrated Radiation and Nuclear Science
[5] Tohoku University,Institute for Materials Research
[6] Agilent Technologies Japan,undefined
[7] Ltd.,undefined
来源：
Journal of Radioanalytical and Nuclear Chemistry | 2018年 / 318卷
关键词：
Uranium; Neptunium; Plutonium; Americium; Curium; Oxygen reaction;
D O I：
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中图分类号：
学科分类号：
摘要：
A study for the quantitative actinide analysis by using a triple quadrupole ICP-MS/MS, Agilent 8900, was carried out. We confirmed the formation percentages of ionic species of each actinide in several kinds of collision/reaction cell modes. It was found that the dominant ions in oxygen gas mode were oxide ions, and the ratio of monoxide ion/dioxide ion increases with atomic number in the case of same oxygen gas flow rate. The percentages of actinide ion and oxide ions depend on the oxygen gas flow rate, and the number of oxygen attached on actinides increases with the oxygen gas flow rate.
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页码：221 / 225
页数：4
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