Saturated vapor pressure over molten mixtures of GaCl 3 and alkali metal chlorides

被引：0
|
作者：
Salyulev A.B. [1 ]
Smolenskii V.V. [1 ]
Moskalenko N.I. [1 ]
机构：
[1] Inst. of High-Temp. Electrochemistry, Ural Division, Russ. Acad. Sci., Yekaterinburg, R.
来源：
Radiochemistry | 2004年 / 46卷 / 4期
关键词：
Chloride; Physical Chemistry; Inorganic Chemistry; Static Method; Partial Pressure;
D O I：
10.1023/B:RACH.0000039115.98837.ec
中图分类号：
学科分类号：
摘要：
Fugacities of GaCl 3 and alkali metal chlorides over molten dilute (up to 3 mol %) solutions of GaCl 3 in LiCl, NaCl, KCl, RbCl, and CsCl were measured at 1100 K by dynamic and indirect static methods. The chemical composition of the saturated vapor over the mixed melts was determined. The partial pressures of the components were calculated. Their values substantially depend on particular alkali metal cation and on the concentration of GaCl 3; their variation allows the parameters of GaCl 3 distillation from the salt melt to be altered in a wide range.
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页码：372 / 376
页数：4
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