Electrochemical properties of molybdenum in individual molten alkali metal chlorides and their mixtures

被引：0
|
作者：
Ivanov A.B. [1 ]
Volkovich V.A. [1 ]
Likhachev P.Y. [1 ]
Vladykin E.N. [1 ]
机构：
[1] Ural Federal University, ul. Mira 19, Yekaterinburg
来源：
Russian Metallurgy (Metally) | 2015年 / 2015卷 / 2期
关键词：
Molybdenum; LiCl; RbCl; CsCl; RUSSIAN Metallurgy;
D O I：
10.1134/S0036029515020081
中图分类号：
学科分类号：
摘要：
The behavior of molybdenum in chloride melts is studied, and the standard potentials of Mo are determined in the melts based on eutectic mixtures LiCl-KCl-CsCl (at 633–1173 K) and NaCl-CsCl (at 793–1023 K), an equimolar NaCl-KCl mixture at 973–1123 K, and individual LiCl, NaCl, KCl, RbCl, and CsCl at 1123 K. The change in the conventional standard Gibbs energy of molybdenum trichloride formation in the NaCl-KCl, NaCl-CsCl, and LiCl-KCl-CsCl melts is calculated. The effect of the cation composition of the salt solvent on the conventional standard electrode potential of molybdenum in the chloride melts is considered. The diffusion coefficients of Mo(III) ions in the LiCl-KCl-CsCl melt are determined. © 2015, Pleiades Publishing, Ltd.
引用
收藏
页码：141 / 146
页数：5
相关论文
共 50 条
  • [1] Electrochemical Properties of Gallium in Molten Alkali Metal Chlorides
    Tokarev, O., V
    Maltsev, D. S.
    Volkovich, V. A.
    [J]. VII INTERNATIONAL YOUNG RESEARCHERS' CONFERENCE - PHYSICS, TECHNOLOGY, INNOVATIONS (PTI-2020), 2020, 2313
  • [2] Electrochemical Properties of Tungsten in Molten Alkali Metal Chlorides
    Ryzhov, A. A.
    Ivanov, A. B.
    Volkovich, V. A.
    [J]. RUSSIAN METALLURGY, 2019, 2019 (02): : 149 - 151
  • [3] Electrochemical Properties of Tungsten in Molten Alkali Metal Chlorides
    A. A. Ryzhov
    A. B. Ivanov
    V. A. Volkovich
    [J]. Russian Metallurgy (Metally), 2019, 2019 : 149 - 151
  • [4] The Electrochemical and Thermodynamic Properties of Dysprosium in Molten Alkali Metal Chlorides
    Novoselova, Alena
    Smolenski, Valeri
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2021, 168 (06)
  • [5] THERMODYNAMIC PROPERTIES OF MOLYBDENUM (3) CHLORIDE IN MOLTEN ALKALI METAL CHLORIDES
    SELIS, SM
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1966, 113 (01) : 37 - +
  • [6] Stability of complex molybdenum(III) ions in molten alkali metal chlorides
    Kamalov, R.V.
    Volkovich, V.A.
    Polovov, I.B.
    Vasin, B.D.
    [J]. Russian Metallurgy (Metally), 2012, 2012 (02) : 114 - 118
  • [7] ELECTROCHEMICAL-BEHAVIOR OF VANADIUM IN MOLTEN ALKALI-METAL CHLORIDES
    SASHININA, OA
    SHKOLNIKOV, SN
    BAIMAKOV, AN
    [J]. JOURNAL OF APPLIED CHEMISTRY OF THE USSR, 1986, 59 (05): : 1039 - 1041
  • [8] PRODUCTION OF ALKALI METAL SULFATES FROM ALKALI METAL CHLORIDES, SULFUR, OXYGEN, AND WATER IN MOLTEN SALT MIXTURES
    CHIN, YR
    ALBRIGHT, LF
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1969, (SEP): : IN12 - &
  • [9] PRODUCTION OF ALKALI METAL SULFATES FROM ALKALI METAL CHLORIDES, SULFUR, OXYGEN, AND WATER IN MOLTEN SALT MIXTURES
    CHIN, YR
    ALBRIGHT, LF
    [J]. INDUSTRIAL & ENGINEERING CHEMISTRY PROCESS DESIGN AND DEVELOPMENT, 1971, 10 (01): : 1 - &
  • [10] Saturated vapor pressure over molten mixtures of GaCl 3 and alkali metal chlorides
    Salyulev A.B.
    Smolenskii V.V.
    Moskalenko N.I.
    [J]. Radiochemistry, 2004, 46 (4) : 372 - 376
12345