La0.75Sr0.25Cr0.5Mn0.5O3−δ-Ce0.8Gd0.2O1.9 composite electrodes as anodes in LaGaO3-based direct carbon solid oxide fuel cellsLa0.75Sr0.25Cr0.5Mn0.5O3−δ–Ce0.8Gd0.2O1.9复合电极用作LaGaO3基直接碳固体氧化物燃料电池阳极的研究

被引:0
|
作者
Tian-yu Chen
Yong-min Xie
Zhi-bin Lu
Liang Wang
Zhe-qin Chen
Xiao-cong Zhong
Jia-ming Liu
Rui-xiang Wang
Zhi-feng Xu
Shao-bo Ouyang
机构
[1] Jiangxi University of Science and Technology,Faculty of Materials Metallurgy and Chemistry
[2] Ganzhou Engineering Technology Research Center of Green Metallurgy and Process Intensification,undefined
[3] Jiangxi College of Applied Technology,undefined
来源
关键词
direct carbon solid oxide fuel cells; anode material; La; Sr; Cr; Mn; O; -Ce; Gd; O; composite electrodes; Ni nanoparticles; 直接碳固体氧化物燃料电池; 阳极材料; La; Sr; Cr; Mn; O; −Ce0.8Gd0.2O1.9复合电极; Ni 纳米颗粒;
D O I
暂无
中图分类号
学科分类号
摘要
Direct carbon solid oxide fuel cells (DC-SOFCs) are promising, green, and efficient power-generating devices that are fueled by solid carbons and comprise all-solid-state structures. Developing suitable anode materials for DC-SOFCs is a substantial scientific challenge. Herein we investigated the use of La0.75Sr0.25Cr0.5Mn0.5O3−δ-Ce0.8Gd0.2O1.9 (LSCM—GDC) composite electrodes as anodes for La0.9Sr0.1Ga0.8Mg0.2O3−δ electrolyte-based DC-SOFCs, with Camellia oleifera shell char as the carbon fuel The LSCM—GDC-anode DC-SOFC delivered a maximum power density of 221 mW/cm2 at 800 °C and it significantly improved to 425 mW/cm2 after Ni nanoparticles were introduced into the LSCM—GDC anode through wet impregnation The microstructures of the prepared anodes were characterized, and the stability of the anode in a DC-SOFC and the influence of catalytic activity on open circuit voltage were studied The above results indicate that LSCM—GDC anode is promising to be applied in DC-SOFCs.
引用
收藏
页码:1788 / 1798
页数:10
相关论文
共 50 条
  • [1] La0.75Sr0.25Cr0.5Mn0.5O3-δ-Ce0.8Gd0.2O1.9 composite electrodes as anodes in LaGaO3-based direct carbon solid oxide fuel cells
    CHEN Tian-yu
    XIE Yong-min
    LU Zhi-bin
    WANG Liang
    CHEN Zhe-qin
    ZHONG Xiao-cong
    LIU Jia-ming
    WANG Rui-xiang
    XU Zhi-feng
    OUYANG Shao-bo
    JOURNAL OF CENTRAL SOUTH UNIVERSITY, 2022, 29 (06) : 1788 - 1798
  • [2] La0.75Sr0.25Cr0.5Mn0.5O3-δ-Ce0.8Gd0.2O1.9复合电极用作LaGaO3基直接碳固体氧化物燃料电池阳极的研究(英文)
    谌田雨
    谢永敏
    卢致斌
    王亮
    陈哲钦
    钟晓聪
    刘嘉铭
    王瑞祥
    徐志峰
    欧阳少波
    Journal of Central South University, 2022, 29 (06) : 1788 - 1798
  • [3] Sulfur tolerance and hydrocarbon stability of La0.75Sr0.25Cr0.5Mn0.5O3/Gd0.2Ce0.8O1.9 composite anode under anodic polarization
    Chen, X. J.
    Liu, Q. L.
    Chan, S. H.
    Brandon, N. P.
    Khor, Khiam Aik
    JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2007, 154 (11) : B1206 - B1210
  • [4] Effect of Ce0.8Sm0.2O1.9 interlayer on the electrochemical performance of La0.75Sr0.25Cr0.5Mn0.5O3-δ-Ce0.8Sm0.2O1.9 composite anodes for intermediate-temperature solid oxide fuel cells
    He, Shoucheng
    Chen, Han
    Li, Ruifeng
    Ge, Lin
    Guo, Lucun
    JOURNAL OF POWER SOURCES, 2014, 253 : 187 - 192
  • [5] (La0.75Sr0.25)0.95(Cr0.5Mn0.5)O3-δ-Ce0.8Gd0.2O1.9 scaffolded composite cathode for high temperature CO2 electroreduction in solid oxide electrolysis cell
    Zhang, Xiaomin
    Song, Yuefeng
    Guan, Fang
    Zhou, Yingjie
    Lv, Houfu
    Liu, Qingxue
    Wang, Guoxiong
    Bao, Xinhe
    JOURNAL OF POWER SOURCES, 2018, 400 : 104 - 113
  • [6] La0.75Sr0.25Cr0.5Mn0.5O3-δ-Ce0.8Sm0.2O1.9 as composite electrodes in symmetric solid electrolyte cells for electrochemical removal of nitric oxide
    Li, Wenjie
    Liu, Xiaozhen
    Yu, Han
    Zhang, Shuyuan
    Yu, Hongbing
    APPLIED CATALYSIS B-ENVIRONMENTAL, 2020, 264
  • [7] La0.75Sr0.25Cr0.5Mn0.5O3-δ-Ce0.8Sm0.2O1.9 as composite electrodes in symmetric solid electrolyte cells for electrochemical removal of nitric oxide
    Li, Wenjie
    Liu, Xiaozhen
    Yu, Han
    Zhang, Shuyuan
    Yu, Hongbing
    Applied Catalysis B: Environmental, 2020, 264
  • [8] Optimization of La0.75Sr0.25Cr0.5Mn0.5O3-δ-Ce0.8Sm0.2O1.9 compositionally graded anode functional layer
    He, Shoucheng
    Dai, Hailu
    Cai, Guifan
    Chen, Han
    Guo, Lucun
    ELECTROCHIMICA ACTA, 2015, 152 : 155 - 160
  • [9] Properties and electrochemical performance of La0.75Sr0.25Cr0.5Mn0.5O3-δ-La0.2Ce0.8O2-δ composite anodes for solid oxide fuel cells
    Rath, Manas K.
    Choi, Byung-Hyun
    Lee, Ki-Tae
    JOURNAL OF POWER SOURCES, 2012, 213 : 55 - 62
  • [10] Direct Utilization of Methanol and Ethanol on La0.75Sr0.25Cr0.5Mn0.5O3−δ Anodes for Solid Oxide Fuel Cells
    Massimiliano Cimenti
    Marco A. Buccheri
    Josephine M. Hill
    Electrocatalysis, 2012, 3 : 59 - 67