Viscosity of Potassium Trioxalato Complexes of Al(III), Fe(III), Co(III), and Cr(III) in Aqueous Solution Between 15° and 35°C

被引:0
|
作者
Jinamoni Bhuyan
Nibaran C. Dey
Inamul Haque
机构
[1] Regional Research Laboratory,
[2] Dibrugarh University,undefined
来源
关键词
Viscosity; complex ions; trioxalato complexes; temperature dependence; coefficients;
D O I
暂无
中图分类号
学科分类号
摘要
The viscosity of dilute aqueous solutions of K3[AI(ox)3]·3H2O, K3[Fe(ox)3]·3H2O, K3[Co(ox)3]·3H2O, and K3[Cr(ox)3]·3H2O complexes, as well as K2(ox)·H2O, were measured between 15 and 35°C. Those of CoCl2, 6H2O, FeCl3, A12(SO4)3·18H2O, and CrCl3·6H2O were measured at 25°C. These data were analyzed by the Jones–Dole equation. The ionic B coefficients of the above complex anions were discussed in terms of ion–solvent interactions and the overall change in ΔB associated with complex formation.
引用
收藏
页码:495 / 505
页数:10
相关论文
共 50 条
  • [21] Structure of Co(III) and Fe(III) transition metal ions in aqueous solution
    Mohammed, Ahmed M.
    BULLETIN OF THE CHEMICAL SOCIETY OF ETHIOPIA, 2006, 20 (01) : 121 - 131
  • [22] REACTION OF GELATIN WITH Cr(III), Al(III) AND Fe(III): INVESTIGATION BY SPECTROFLUORIMETRY
    Jiping, Chen
    Ying, Gong
    Wuyong, Chen
    JOURNAL OF THE SOCIETY OF LEATHER TECHNOLOGISTS AND CHEMISTS, 2008, 92 (06): : 245 - 249
  • [23] Reaction of gelatin with Cr(III), Al(III) and Fe(III): Investigation by spectrofluorimetry
    Key Laboratory of Leather Chemistry and Engineering, Ministry of Education, Sichuan University, Chengdu 610065, China
    J Soc Leather Technol Chem, 2008, 6 (245-249):
  • [24] Physicochemical parameters of collective hydrolysis of Cr(III) and Al(III) cations in aqueous solution
    Kirillov, A.M.
    Karabach, E.A.
    Kopylovich, M.N.
    Baev, A.L.
    Zhurnal Neorganicheskoj Khimii, 2003, 48 (03): : 516 - 521
  • [25] Physicochemical parameters of collective hydrolysis of Cr(III) and Al(III) cations in aqueous solution
    Kirillov, AM
    Karabach, EA
    Kopylovich, MN
    Baev, AK
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2003, 48 (03) : 443 - 447
  • [26] Chromium Removal from Aqueous Solutions by Co-precipitation with Al (III), Fe (III) and Al (III) / Fe (III) Effect of pH and Competitive Ions
    Merabet, Souad
    Boukhalfa, Chahrazed
    RESEARCH JOURNAL OF PHARMACEUTICAL BIOLOGICAL AND CHEMICAL SCIENCES, 2015, 6 (02): : 1715 - 1720
  • [27] COMPLEXES OF MN(II), CR(III) AND FE(III) WITH THIOCARBOHYDRAZONES
    SHIVAPRASAD, KH
    PATIL, SA
    PATIL, BR
    KULKARNI, VH
    ACTA CHIMICA HUNGARICA-MODELS IN CHEMISTRY, 1986, 122 (02): : 169 - 173
  • [28] V(III), CR(III), MN(III) AND FE(III) COMPLEXES OF DISALICYLALDIMINE OXAMIDE, MALONAMINE AND SUCCINAMIDE
    NARANG, KK
    YADAV, US
    CURRENT SCIENCE, 1980, 49 (22): : 852 - 855
  • [29] PHOTOCALORIMETRY .3. ENTHALPIES OF SUBSTITUTION-REACTIONS OF SOME CR(III) AMMINES AND CR(III) AND CO(III) CYANO COMPLEXES IN AQUEOUS-SOLUTION
    NAKASHIMA, M
    ADAMSON, AW
    JOURNAL OF PHYSICAL CHEMISTRY, 1982, 86 (15): : 2910 - 2912
  • [30] HETEROPOLYNUCLEAR COMPLEXES OF FE(III) AND CR(III) IN ACETOAQUEOUS SOLUTIONS
    NIKOLSKII, BP
    PALCHEVS.VV
    PENDIN, AA
    YAKUBOV, KM
    OFFENGEN.EY
    KALONTAR.EY
    DOKLADY AKADEMII NAUK SSSR, 1971, 200 (01): : 128 - +