Physicochemical parameters of collective hydrolysis of Cr(III) and Al(III) cations in aqueous solution

被引:0
|
作者
Kirillov, AM [1 ]
Karabach, EA
Kopylovich, MN
Baev, AK
机构
[1] Minsk Res Inst Powder Met Pilot Plant, Minsk, BELARUS
[2] Lisbon Tech Inst, Lisbon, Portugal
[3] Russian Acad Sci, Ivanovo Inst Chem Solut, Ivanovo, Russia
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D O I
暂无
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The kinetic parameters for the collective hydrolysis of Cr3+ and Al3+ cations in aqueous solutions of different neutralization degrees are determined. The cancellation effect between the activation energy and the frequency factor in hydroxopolymerization reactions is observed. The thermodynamic characteristics of collective hydrolysis and their correlations with the kinetic parameters are obtained.
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页码:443 / 447
页数:5
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