Viscosity of Potassium Trioxalato Complexes of Al(III), Fe(III), Co(III), and Cr(III) in Aqueous Solution Between 15° and 35°C

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作者
Jinamoni Bhuyan
Nibaran C. Dey
Inamul Haque
机构
[1] Regional Research Laboratory,
[2] Dibrugarh University,undefined
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关键词
Viscosity; complex ions; trioxalato complexes; temperature dependence; coefficients;
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摘要
The viscosity of dilute aqueous solutions of K3[AI(ox)3]·3H2O, K3[Fe(ox)3]·3H2O, K3[Co(ox)3]·3H2O, and K3[Cr(ox)3]·3H2O complexes, as well as K2(ox)·H2O, were measured between 15 and 35°C. Those of CoCl2, 6H2O, FeCl3, A12(SO4)3·18H2O, and CrCl3·6H2O were measured at 25°C. These data were analyzed by the Jones–Dole equation. The ionic B coefficients of the above complex anions were discussed in terms of ion–solvent interactions and the overall change in ΔB associated with complex formation.
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页码:495 / 505
页数:10
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