Materials for all-solid-state thin-film rechargeable lithium batteries by sol-gel processing

被引:0
|
作者
M. Vinod
D. Bahnemann
机构
[1] Institut für Solarenergieforschung,
[2] Hameln/Emmerthal (ISFH),undefined
[3] Aussenstelle,undefined
[4] Sokelantstrasse 5,undefined
[5] 30165 Hannover,undefined
[6] Present address: Department of Chemistry,undefined
[7] University of Missouri-St. Louis,undefined
[8] St. Louis,undefined
[9] MO 63121-4499,undefined
[10] E-mail: -vinodm@msx.umsl.edu,undefined
[11] Tel.: +1-314-5164374,undefined
[12] Fax: +1-314-5165342,undefined
关键词
Thin Films Lithium batteries Sol-gel processing;
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学科分类号
摘要
A novel all-solid-state thin-film lithium battery has been fabricated by spin coating V2O5 and LiClO4-SiO2 thin films on a stainless steel substrate. The LiClO4-SiO2 electrolyte has been synthesized using a new sol-gel route and it has been characterized by electrochemical impedance spectroscopy. The Li+ ion conductivity of the spin-coated thin film thus measured is in the order of 10–6 S/cm, at 25 °C, which is sufficient for electrolytes in such thin-film batteries. The battery shows a typical discharge capacity of about 150 µAh/mg and satisfactory cathodic efficiency and cycle-life performance.
引用
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页码:498 / 501
页数:3
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