Catalytic epoxidation of α-pinene over bifunctional mesoporous molecular sieves

被引:0
|
作者
D. Trong On
M.P. Kapoor
P.N. Joshi
L. Bonneviot
S. Kaliaguine
机构
来源
Catalysis Letters | 1997年 / 44卷
关键词
Epoxidation; Molecular Sieve; TBHP; Trivalent Cation; Mesoporous Molecular Sieve;
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摘要
Bifunctional titanium-mesoporous molecular sieves containing different trivalent ions, e.g. B3+, Al3+ or Fe3+, were synthesized and characterized. These catalysts, which contain both acid and oxidizing catalytic sites, are very active in epoxidation of bulky olefins and highly selective in diol formation. A reasonably good stability and re-usability are also observed.
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页码:171 / 176
页数:5
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