Catalytic epoxidation of α-pinene over bifunctional mesoporous molecular sieves

被引:0
|
作者
D. Trong On
M.P. Kapoor
P.N. Joshi
L. Bonneviot
S. Kaliaguine
机构
来源
Catalysis Letters | 1997年 / 44卷
关键词
Epoxidation; Molecular Sieve; TBHP; Trivalent Cation; Mesoporous Molecular Sieve;
D O I
暂无
中图分类号
学科分类号
摘要
Bifunctional titanium-mesoporous molecular sieves containing different trivalent ions, e.g. B3+, Al3+ or Fe3+, were synthesized and characterized. These catalysts, which contain both acid and oxidizing catalytic sites, are very active in epoxidation of bulky olefins and highly selective in diol formation. A reasonably good stability and re-usability are also observed.
引用
收藏
页码:171 / 176
页数:5
相关论文
共 50 条
  • [21] Reactive oxygen species in epoxidation reactions over titanosilicate molecular sieves
    Shetti, VN
    Manikandan, P
    Srinivas, D
    Ratnasamy, P
    JOURNAL OF CATALYSIS, 2003, 216 (1-2) : 461 - 467
  • [22] Catalytic epoxidation of β-pinene with aqueous hydrogen peroxide
    V. V. Fomenko
    O. V. Bakhvalov
    V. F. Kollegov
    N. F. Salakhutdinov
    Russian Journal of General Chemistry, 2017, 87 : 1675 - 1679
  • [23] Catalytic epoxidation of β-pinene with aqueous hydrogen peroxide
    Fomenko, V. V.
    Bakhvalov, O. V.
    Kollegov, V. F.
    Salakhutdinov, N. F.
    RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2017, 87 (08) : 1675 - 1679
  • [24] PROCEDURE FOR THE CATALYTIC ASYMMETRIC EPOXIDATION OF ALLYLIC ALCOHOLS IN THE PRESENCE OF MOLECULAR-SIEVES
    HANSON, RM
    SHARPLESS, KB
    JOURNAL OF ORGANIC CHEMISTRY, 1986, 51 (10): : 1922 - 1925
  • [25] Alkylation and disproportionation of aromatic hydrocarbons over mesoporous molecular sieves
    Cejka, J
    Krejcí, A
    Zilková, N
    Dedecek, J
    Hanika, J
    MICROPOROUS AND MESOPOROUS MATERIALS, 2001, 44 : 499 - 507
  • [26] Direct synthesis of AlSBA mesoporous molecular sieves:: characterization and catalytic activities
    Yue, YH
    Gédéon, A
    Bonardet, JL
    Melosh, N
    D'Espinose, JB
    Fraissard, J
    CHEMICAL COMMUNICATIONS, 1999, (19) : 1967 - 1968
  • [27] Catalytic olefin epoxidation over cobalt(II)-containing mesoporous silica by molecular oxygen in dimethylformamide medium
    Bhunia, Susmita
    Jana, Sreyashi
    Saha, Debraj
    Dutta, Buddhadeb
    Koner, Subratanath
    CATALYSIS SCIENCE & TECHNOLOGY, 2014, 4 (06) : 1820 - 1828
  • [28] Synthesis of mesoporous hexagonal titanium aluminophosphate molecular sieves and their catalytic applications
    Kapoor, MP
    Raj, A
    APPLIED CATALYSIS A-GENERAL, 2000, 203 (02) : 311 - 319
  • [29] Functionalization of HMS mesoporous molecular sieves and their base-catalytic performance
    Yang, C
    NANOPOROUS MATERIALS IV, 2005, 156 : 229 - 236
  • [30] Catalytic properties of mesoporous molecular sieves prepared by neutral surfactant assembly
    Pinnavaia, TJ
    Zhang, WZ
    MESOPOROUS MOLECULAR SIEVES 1998, 1998, 117 : 23 - 36