Building bridges

被引：0
|
作者：
Cara E. Brocklehurst
Edward A. Anderson
机构：
[1] Novartis Institutes for Biomedical Research,Global Discovery Chemistry Department
[2] University of Oxford,Department of Chemistry
来源：
Nature Chemistry | 2021年 / 13卷
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学科分类号：
摘要：
Methods for the synthesis of bicyclo[1.1.1]pentanes (BCPs) typically rely on the release of strain energy, but these routes cannot easily introduce substituents on the BCP bridges. Now, an intramolecular coupling gives access to multi-substituted BCPs, through the synthesis of bridge-substituted bicycloalkyl boronic esters.
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页码：928 / 930
页数：2
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