Synthesis and structural characterization of a novel organic-inorganic supermoleculer of [FeII(Phen)3]L2 · 2H2O complex

被引：0

作者：

Gao E.J. ^{[1
]}

Zhang Y. ^{[1
]}

Guan F. ^{[1
]}

Su M. ^{[1
]}

Zhang M. ^{[1
]}

Gao X.N. ^{[1
]}

Guo M.J. ^{[1
]}

Shi Q.Z. ^{[1
]}

Sun T.D. ^{[1
]}

He W.X. ^{[1
]}

机构：

[1] Coordination Chemistry Laboratory, Shenyang Institute of Chemical Technology, Shenyang

来源：

Russian Journal of Coordination Chemistry | 2010年 / 36卷 / 8期

关键词：

Phen; Coordination Chemistry; Iron Atom; Title Complex; Distorted Octahedral Geometry;

D O I：

10.1134/S1070328410080099

中图分类号：

学科分类号：

摘要：

A new organic-inorganic complex [FeII(Phen)3]L 2-2H2O (Phen = 1,10-phenanthroline, L = 2-mercaptonicotinic acid) was synthesized and characterized. The crystal structure of the complex was determined by single-crystal X-ray diffraction, crystallizing in orthorhombic crystal system, space group Pba2 with the unit cell parameters a = 13.4711(11), b = 17.0021(14), c = 11.7026(9) Å, and Z = 2. The Fe(II) atom wa s six-coordinated with N(1), N(1A), N(2), N(2A), N(3), and N(3A) from three Phen ligands and formed a slightly distorted octahedral geometry. The base units form a one-dimensional chain via π-π-stacking interaction between 2-mercaptonicotinic acid fragments. A new 3D layered compound was obtained through hydrogen bonding. © Pleiades Publishing, Ltd., 2010.

引用

页码：610 / 614

页数：4

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