Synthesis and structural characterization of a novel organic-inorganic supermoleculer of [FeII(Phen)3]L2 · 2H2O complex

被引：0
|
作者：
Gao E.J. [1 ]
Zhang Y. [1 ]
Guan F. [1 ]
Su M. [1 ]
Zhang M. [1 ]
Gao X.N. [1 ]
Guo M.J. [1 ]
Shi Q.Z. [1 ]
Sun T.D. [1 ]
He W.X. [1 ]
机构：
[1] Coordination Chemistry Laboratory, Shenyang Institute of Chemical Technology, Shenyang
来源：
Russian Journal of Coordination Chemistry | 2010年 / 36卷 / 8期
关键词：
Phen; Coordination Chemistry; Iron Atom; Title Complex; Distorted Octahedral Geometry;
D O I：
10.1134/S1070328410080099
中图分类号：
学科分类号：
摘要：
A new organic-inorganic complex [FeII(Phen)3]L 2-2H2O (Phen = 1,10-phenanthroline, L = 2-mercaptonicotinic acid) was synthesized and characterized. The crystal structure of the complex was determined by single-crystal X-ray diffraction, crystallizing in orthorhombic crystal system, space group Pba2 with the unit cell parameters a = 13.4711(11), b = 17.0021(14), c = 11.7026(9) Å, and Z = 2. The Fe(II) atom wa s six-coordinated with N(1), N(1A), N(2), N(2A), N(3), and N(3A) from three Phen ligands and formed a slightly distorted octahedral geometry. The base units form a one-dimensional chain via π-π-stacking interaction between 2-mercaptonicotinic acid fragments. A new 3D layered compound was obtained through hydrogen bonding. © Pleiades Publishing, Ltd., 2010.
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页码：610 / 614
页数：4
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