Synthesis and structural characterization of a novel organic-inorganic supermoleculer of [FeII(Phen)3]L2 · 2H2O complex

被引：0
|
作者：
Gao E.J. [1 ]
Zhang Y. [1 ]
Guan F. [1 ]
Su M. [1 ]
Zhang M. [1 ]
Gao X.N. [1 ]
Guo M.J. [1 ]
Shi Q.Z. [1 ]
Sun T.D. [1 ]
He W.X. [1 ]
机构：
[1] Coordination Chemistry Laboratory, Shenyang Institute of Chemical Technology, Shenyang
来源：
Russian Journal of Coordination Chemistry | 2010年 / 36卷 / 8期
关键词：
Phen; Coordination Chemistry; Iron Atom; Title Complex; Distorted Octahedral Geometry;
D O I：
10.1134/S1070328410080099
中图分类号：
学科分类号：
摘要：
A new organic-inorganic complex [FeII(Phen)3]L 2-2H2O (Phen = 1,10-phenanthroline, L = 2-mercaptonicotinic acid) was synthesized and characterized. The crystal structure of the complex was determined by single-crystal X-ray diffraction, crystallizing in orthorhombic crystal system, space group Pba2 with the unit cell parameters a = 13.4711(11), b = 17.0021(14), c = 11.7026(9) Å, and Z = 2. The Fe(II) atom wa s six-coordinated with N(1), N(1A), N(2), N(2A), N(3), and N(3A) from three Phen ligands and formed a slightly distorted octahedral geometry. The base units form a one-dimensional chain via π-π-stacking interaction between 2-mercaptonicotinic acid fragments. A new 3D layered compound was obtained through hydrogen bonding. © Pleiades Publishing, Ltd., 2010.
引用
收藏
页码：610 / 614
页数：4
相关论文
共 50 条
  • [1] Synthesis and structural characterization of a novel organic-inorganic supermoleculer of [FeII(Phen)3]L2 • 2H2O complex
    Chen, G.
    Niu, H. Y.
    Wang, W.
    Wang, J. P.
    Niu, J. Y.
    RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2010, 36 (08) : 605 - 609
  • [2] Synthesis and Characterization of a Novel Coordination Polymer {[Mn(L)(Phen)2] • 2H2O}n
    Gao, E. J.
    Liu, S. H.
    Sun, T. D.
    Lin, L.
    Wang, R. S.
    Zhang, Y. X.
    Su, M.
    Zhang, M.
    RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2011, 37 (06) : 439 - 443
  • [3] Synthesis and Characterization of PVP/Eu4/3L(phen)•2H2O Luminescent Complex
    Ren, Huijuan
    Yang, Hua
    Sun, Dehui
    Cui, Zhenfeng
    Hong, Guangyan
    FRONTIERS OF MANUFACTURING AND DESIGN SCIENCE II, PTS 1-6, 2012, 121-126 : 1500 - +
  • [4] Synthesis and crystal structure of an organic-inorganic complex [Cu(DMF)3(H2O)2]2[SiMo12O40]•2H2O
    Wang Jingping
    Du Xiaodi
    Duan Xianying
    Niu Jingyang
    RARE METALS, 2007, 26 (04) : 377 - 384
  • [5] Synthesis and crystal structure of an organic-inorganic complex [Cu(DMF)3(H2O)2]2[SiMo12O40]·2H2O
    WANG Jingping1)
    RareMetals, 2007, (04) : 377 - 384
  • [6] Synthesis and characterization of a novel coordination polymer {[Mn(L)(Phen)2] · 2H2O}n1
    E. J. Gao
    S. H. Liu
    T. D. Sun
    L. Lin
    R. S. Wang
    Y. X. Zhang
    M. Su
    M. Zhang
    Russian Journal of Coordination Chemistry, 2011, 37 : 439 - 443
  • [7] Synthesis and Structural Characterization of {[Mn（phen）2（OAc）(H2O)]ClO4}2H2O
    ZHANG Xiao-Feng CHEN Feng HUANG De-Guang CHEN Chang-Neng LIU Qiu-Tian② (State Key Laboratory of Structural Chemistry
    结构化学, 2003, (02) : 151 - 154
  • [8] Synthesis and Structural Characterization of Adduct Cu2（phen）2·3（FCA）·（ClO4）·2H2O
    Jia Xiang YANG
    YU Peng TIAN
    Qing Liang LIU
    Yong Shu XIE
    Hoong Kun FUN(Department of Chemistry
    Chinese Chemical Letters, 2000, (07) : 639 - 640
  • [9] Synthesis and structural characterization of adduct Cu2(phen)2 • 3(FCA) • (C104) • 2H2O
    Yang, JX
    Tian, YP
    Liu, XL
    Xie, YS
    Fun, HK
    CHINESE CHEMICAL LETTERS, 2000, 11 (07) : 639 - 640
  • [10] Synthesis and characterization of complex of NdL3 • 2H2O
    Yang, YL
    Li, X
    Zhao, KP
    Zhao, YP
    SPECTROSCOPY AND SPECTRAL ANALYSIS, 2000, 20 (03) : 322 - 323
12345