Thermal and Spectroscopy Investigation of Cyclopalladated Compounds of the Type [Pd(C13H10N)(μ-X)]2, (X=H3CCOO, NCO, SCN, CN)

被引：0
|
作者：
A. M. Santana
A. E. Mauro
H. E. Zorel
M. P. D. Mattioli
V. A. de Lucca Neto
机构：
[1] UNESP,Instituto de Química
来源：
Journal of Thermal Analysis and Calorimetry | 2002年 / 67卷
关键词：
cyclopalladated; IR spectroscopy; pseudohalogens; thermal analysis; X-ray diffraction;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The dimeric compound [Pd(bzan)(μ-OOCCH3)]2 (1) (bzan=N-benzylideneaniline) reacts with KX, in methanol/acetone (2:1), affording the analogous dimeric pseudohalogen-bridged species [Pd(bzan)(μ-X)]2 [X=NCO(2),SCN(3), CN(4)]. The compounds were characterized by elemental analysis, infrared spectroscopy, NMR and thermogravimetric analysis. IR data for 2–4 showed bands typical of coordinated pseudohalogen ligands clearly indicating the occurrence of the exchange reaction. Their thermal behaviour was investigated and suggested that their stability is influenced by the bridging ligand. The thermal stability decreased in the order[Pd(bzan)(μ-CN)]2>[Pd(bzan)(μ-SCN)]2>[Pd(bzan)(μ-OOCCH3)]2>[Pd(bzan)(μ-NCO)]2. X-ray results showed the formation of Pd° as final decomposition product.
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页码：425 / 431
页数：6
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