X-ray structure of [(μ-H)Os3(CO)10(μ-1,8-η2-C9H6N)]

被引：8

作者：

Akter, J

Hossain, GMG

Kabir, SE

Abdul Malik, KM ^{[1
]}

机构：

[1] Cardiff Univ, Dept Chem, POB 912,Pk Pl, Cardiff CF10 3TB, S Glam, Wales

[2] Jahangirnagar Univ, Dept Chem, Dhaka 1342, Bangladesh

来源：

JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | 2000年 / 30卷 / 12期

基金：

英国工程与自然科学研究理事会;

关键词：

X-ray structure; triosmium cluster; decacarbonyl; quinoline;

D O I：

10.1023/A:1013268023526

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

Decacarbonyl-mu-hydrido-mu-1,8-eta(2)-quinoline-triosmium crystallizes in the triclinic space group P (1) over bar with a = 7.8551(6), b = 9.1283(8), c = 16.7915(8) Angstrom. alpha = 74.788(2), beta = 88.086(2), gamma = 66.392(3), V = 1062.22(13)degrees Angstrom(3), T = 150 K, and Z = 2. The molecule consists of an Os-3 triangle with the hydride and the heterocyclic ligand bridging the same Os-Os edge. The heterocyclic ligand is coordinated through the C(8) carbon and nitrogen atoms in a new mu-1,8-eta(2)-bonding mode. The Os-Os distances lie in the close range 2.8837(4)-2.9034(4) Angstrom with an average value of 2.892(7) Angstrom.

引用

页码：773 / 776

页数：4

共 50 条

[1] X-ray structure of [(μ-H)Os3(CO)10(μ-1,8-η2-C9H6N)]
Jakia Akter
G.M. Golzar Hossain
Shariff E. Kabir
K.M. Abdul Malik
[J]. Journal of Chemical Crystallography, 2000, 30 : 773 - 776
[2] X-ray diffraction structures of two isomeric decacarbonyltriosmium compounds of quinoxaline, [(μ-H)Os3(CO)10(μ-1,8,η2-C8H5N2)] and [(μ-H)Os3(CO)10)(μ-1, 2-η2-C8H5N2)]
Begum, N
Das, UK
Hossain, GMG
Hyder, MI
Kabir, SE
[J]. INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 2005, 44 (10): : 1988 - 1994
[3] Osmium clusters derived from the reactions of [Os3(CO)10(CH3CN)2] with aminothiazole compounds:: X-ray structures of [Os3(μ-H)(CO)10(μ-C8H7N2S], [Os3(μ-H)(CO)9(μ3-η2-C3H5N2S)] and [Os3(μ-H)(CO)9(μ3-η2-C6H7ON2S)]
D'Ornelas, L
Castrillo, T
Hernández, LD
Narayan, A
Atencio, R
[J]. INORGANICA CHIMICA ACTA, 2003, 342 : 1 - 8
[4] Reactions of [(μ-H)Os3(CO)8-{Ph2PCH2P(Ph)C6H4}] and [Os3(CO)10 (μ-dppm)] with 2-mercaptoimidozole, 2-mercaptobenzimidazole and 2-mercaptobenzothiazole:: X-ray structure of [(μ-H)Os3(CO)8(μ-dppm)(μ-η1-SN2C3H3)]
Begum, N
Hassan, MM
Hossain, GMG
Kabir, SE
[J]. INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 2005, 44 (04): : 723 - 728
[5] Reactivity of electron-deficient triosmium quinoline cluster [Os3(CO)9(μ3-η2-C9H6N)(μ-H)] with alkynes
Ghosh, Shishir
Al-Mamun, Md Rafique
Hossain, G. M. Golzar
Kabir, Shariff E.
[J]. INORGANICA CHIMICA ACTA, 2011, 378 (01) : 307 - 310
[6] Reactions of unsaturated quinoline triosmium clusters [Os3(CO)9(μ3-η2-C9H5(4-R)N)(μ-H)] (R = Me or H) with tetramethylthiourea:: X-ray structures of [Os3(CO)8(μ-η2-C9H5(4-Me)N) (η2-SC(NMe2NCH2Me)(μ-H)2] and [Os3(CO)9 (μ-η2-C9H6N)(η1-SC(NMe2)2)(μ-H)]
Begum, N
Bennett, DW
Hossain, GMG
Kabir, SE
Sharmin, A
Haworth, DT
Siddiquee, TA
Rosenberg, E
[J]. JOURNAL OF CLUSTER SCIENCE, 2005, 16 (03) : 413 - 428
[7] Reactions of Unsaturated Quinoline Triosmium Clusters [Os3(CO)9(μ3-η2-C9H5(4-R)N)(μ-H)] (R=Me or H) with Tetramethylthiourea: X-ray Structures of [Os3(CO)8(μ-η2-C9H5(4-Me)N)(η2-SC(NMe2NCH2Me)(μ-H)2] and [Os3(CO)9(μ-η2-C9H6N)(η1-SC(NMe2)2)(μ-H)]
Noorjahan Begum
Dennis W. Bennett
G. M. Golzar Hossain
Shariff E. Kabir
Ayesha Sharmin
Daniel T. Haworth
Tasneem A. Siddiquee
Edward Rosenberg
[J]. Journal of Cluster Science, 2005, 16 : 413 - 428
[8] Reactions of [(μ-H)Os3(CO)10(μ-OMe)] and [(μ-H)Os3(CO)9(μ-OMe)(MeCN)] with dppm, dppe, dppp, and PPh2H:: X-ray crystal structures of [(μ-H)Os3(CO)8(μ-OMe)-(μ2-η2-dppm)] and [(μ-H)Os3(CO)9(μ-OMe)(PPh2H)]
Kabir, SE
Mottalib, MA
Hossain, GMG
Nordlander, E
Rosenberg, E
[J]. POLYHEDRON, 2006, 25 (01) : 95 - 104
[9] Reactivity of [Os3(CO)10(NCMe)2] and [Os3(CO)10(μ-Cl)(μ-AuPPh3)] with 4-mercaptopyridine:: X-ray structure of [Os3(CO)10(μ-H)(μ-SC5H4N)] and [Os3(CO)10(μ-AuPPh3)(μ-SC5H4N)]
Sanchez-Cabrera, Gloria
Zuno-Cruz, Francisco J.
Ordonez-Flores, Berenice A.
Rosales-Hoz, Maria J.
Leyva, Marco A.
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2007, 692 (11) : 2138 - 2147
[10] Reactions of triosmium clusters with indole: X-ray structures of [Os3(CO)10(μ-OH)(μ-OMeCO)] and [Os3(μ-H)(CO)10(μ-1, 2-η2-NC8H6)]
Noorjahan Begum
Md. Iqbal Hyder
G. M. Golzar Hossain
Shariff E. Kabir
Shafali R. Karmakar
[J]. Journal of Chemical Crystallography, 2005, 35 : 799 - 807

← 1 2 3 4 5 →