Synthesis and Characterization of 1,8-bis(ferrocenylmethyl)-5,5,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane, a Macrocyclic Ligand and its Complexes

被引：0

作者：

Wen Ma

Yu-Peng Tian

Sheng-Yi Zhang

Jie-Ying Wu

Hoong-Kun Fun

Suchada Chantrapromma

机构：

[1] Anhui University,Department of Chemistry

[2] Universiti Sains Malaysia,X

来源：

Transition Metal Chemistry | 2006年 / 31卷

关键词：

Hydrogen; Mass Spectrum; Catalysis; Absorption Spectrum; Hydrogen Atom;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

A new diferrocenyl-substituted macrocyclic ligand (H2L) and its complexes ML(M = CuII, NiII, ZnII, CdII) were prepared and characterized by IR, elemental analysis, absorption spectra and FAB mass spectra. The ferrocenyl-substituted macrocyclic ligand was characterized by single crystal X-ray diffraction analysis. The superconjugative effect of the cyclopentadienyl (CP) rings increase the activity of the hydrogen atoms in the tetra-azacyclotetradecane macrocyclic ligand. The imine nitrogen atoms lose two protons and coordinate to the metal. The electrochemical properties of these compounds are discussed.

引用

页码：97 / 102

页数：5

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