Crystal structure of cis-[PdCl2(CNMes)2]

被引：0
|
作者：
M. A. Kinzhalov
A. A. Zolotarev
V. P. Boyarskiy
机构：
[1] St. Petersburg State University,
来源：
Journal of Structural Chemistry | 2016年 / 57卷
关键词：
palladium complexes; isocyanides;
D O I：
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学科分类号：
摘要：
The interaction between PdCl2(CH3CN)2 and 2,4,6-Me3C6H2NC (MesNC) proceeds with the substitution of acetonitrile ligands and leads to the synthesis of a cis-[PdCl2(MesNC)2] complex. The structure of this compound is determined by single crystal X-ray diffraction (XRD). The complex has a slightly distorted square-planar structure of the metal center with two cis-positioned isocyanide ligands. In both CN isocyanide moieties the triple bonds have lengths similar to the lengths of the respective bonds in other isocyanide complexes. In the structure, the cis-[PdCl2(MesNC)2] complexes are bound by weak С–H∙∙∙Cl hydrogen bonds and π-stacking interactions.
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页码：822 / 825
页数：3
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