Synthesis Optimization and Catalytic Activity Screening of Industrially Relevant Ruthenium-Based Metathesis Catalysts

被引：0
|
作者：
Angelino Doppiu
Frederic Caijo
Fabien Tripoteau
Savinien Bompard
Christophe Crévisy
Marc Mauduit
机构：
[1] Umicore AG & Co. KG,Precious Metals Chemistry
[2] Ecole Nationale Supérieure de Chimie de Rennes,OMEGA CAT SYSTEM Sarl
[3] Ecole Nationale Supérieure de Chimie de Rennes,CNRS, UMR 6226
来源：
Topics in Catalysis | 2014年 / 57卷
关键词：
Olefin metathesis; Ruthenium; Industrial catalyst synthesis; Terpenes; Fragrances; Fatty esters;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Olefin metathesis is a powerful catalytic reaction that has a huge potential in the pharmaceutical, polymer and specialty chemicals industries. Cost-effective industrial applications require large-scale availability of catalyst precursors which combine high activity, high selectivity and long life-time. Among the known numerous families of olefin metathesis catalysts, the Umicore M7-catalyst family represents a novel class of Hoveyda-type complexes showing excellent chemical stabilities and modular activity profiles. Relevant aspects related to their industrial synthesis as well as their catalytic performance in valuable olefin metathesis transformations are overviewed here.
引用
收藏
页码：1351 / 1358
页数：7
相关论文
共 50 条
  • [41] Molecules of ruthenium-based olefin metathesis catalysts as two- and three-photon absorbers
    Wierzbicka, Celina
    Nyk, Marcin
    Skowerski, Krzysztof
    Samoc, Marek
    [J]. DALTON TRANSACTIONS, 2012, 41 (43) : 13258 - 13260
  • [42] Novel η3-vinylcarbene complexes derived from ruthenium-based olefin metathesis catalysts
    Trnka, TM
    Day, MW
    Grubbs, RH
    [J]. ORGANOMETALLICS, 2001, 20 (18) : 3845 - 3847
  • [43] Ruthenium-based NHC-arene systems as ring-opening metathesis polymerisation catalysts
    Ledoux, Nele
    Allaert, Bart
    Verpoort, Francis
    [J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2007, (35) : 5578 - 5583
  • [44] Ruthenium-based catalysts for the ring-opening metathesis polymerization (ROMP) of functionalized cyclic olefins
    Delaude, L
    Jan, D
    Simal, F
    Demonceau, A
    Noels, AF
    [J]. MACROMOLECULAR SYMPOSIA, 2000, 153 : 133 - 144
  • [45] Unexpected results of a turnover number (TON) study utilising ruthenium-based olefin metathesis catalysts
    Maechling, S
    Zaja, M
    Blechert, S
    [J]. ADVANCED SYNTHESIS & CATALYSIS, 2005, 347 (10) : 1413 - 1422
  • [46] Influence of selenium on the catalytic properties of ruthenium-based cluster catalysts for oxygen reduction
    Bron, M
    Bogdanoff, P
    Fiechter, S
    Dorbandt, I
    Hilgendorff, M
    Schulenburg, H
    Tributsch, H
    [J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2001, 500 (1-2): : 510 - 517
  • [47] Ruthenium-based olefin metathesis catalysts bearing new N-heterocyclic carbenes.
    Anderson, DR
    Grubbs, RH
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2005, 229 : U989 - U989
  • [48] Syntheses and Applications of Indol-2-ylidene-Ligated Ruthenium-Based Olefin Metathesis Catalysts
    Kim, Minseop
    Kim, Hyunho
    Kim, Seyong
    Hong, Sukwon
    Lee, Eunsung
    [J]. ORGANOMETALLICS, 2022, 41 (15) : 1905 - 1910
  • [49] Boron nitride: A novel support for ruthenium-based ammonia synthesis catalysts
    Jacobsen, CJH
    [J]. JOURNAL OF CATALYSIS, 2001, 200 (01) : 1 - 3
  • [50] Toward understanding the high activity of ruthenium-based olefin metathesis catalysts coordinated with N-heterocyclic carbene ligands.
    Grubbs, RH
    Trnka, TM
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2000, 219 : U790 - U790
12345