Synthesis Optimization and Catalytic Activity Screening of Industrially Relevant Ruthenium-Based Metathesis Catalysts

被引：0
|
作者：
Angelino Doppiu
Frederic Caijo
Fabien Tripoteau
Savinien Bompard
Christophe Crévisy
Marc Mauduit
机构：
[1] Umicore AG & Co. KG,Precious Metals Chemistry
[2] Ecole Nationale Supérieure de Chimie de Rennes,OMEGA CAT SYSTEM Sarl
[3] Ecole Nationale Supérieure de Chimie de Rennes,CNRS, UMR 6226
来源：
Topics in Catalysis | 2014年 / 57卷
关键词：
Olefin metathesis; Ruthenium; Industrial catalyst synthesis; Terpenes; Fragrances; Fatty esters;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Olefin metathesis is a powerful catalytic reaction that has a huge potential in the pharmaceutical, polymer and specialty chemicals industries. Cost-effective industrial applications require large-scale availability of catalyst precursors which combine high activity, high selectivity and long life-time. Among the known numerous families of olefin metathesis catalysts, the Umicore M7-catalyst family represents a novel class of Hoveyda-type complexes showing excellent chemical stabilities and modular activity profiles. Relevant aspects related to their industrial synthesis as well as their catalytic performance in valuable olefin metathesis transformations are overviewed here.
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页码：1351 / 1358
页数：7
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