A cellulose-supported Mn(salen)Cl complex as an efficient heterogeneous catalyst for the selective oxidation of benzylic alcohols

被引：0

作者：

Mohammad Ali Nasseri

Arezou Mohammadinezhad

Mehri Salimi

机构：

[1] University of Birjand,Department of Chemistry, College of Sciences

来源：

Journal of the Iranian Chemical Society | 2015年 / 12卷

关键词：

[Mn(salen)Cl-cellulose]; Cellulose; Oxone; Oxidation;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

[Mn(salen)Cl-cellulose] was synthesized by immobilization of homogeneous Mn(salen)Cl complex on cellulose and characterized by FT-IR, TGA and atomic absorption spectroscopy. The resulted catalyst exhibited moderate to high reactivity in the oxidation of benzylic alcohols into carbonyl compounds using oxone as oxidant in ambient conditions. The catalytic activity of Mn(salen)Cl and [Mn(salen)Cl-cellulose] in this reaction was investigated. The heterogeneous catalyst showed higher catalytic activity with respect to neat Mn(salen)Cl complex.

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页码：81 / 86

页数：5

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