An oxidovanadium(IV) complex having a perrhenato ligand: An efficient catalyst for aerobic oxidation reactions of benzylic and propargylic alcohols

被引：10
|
作者：
Kobayashi, Daiki [1 ]
Kodama, Shintaro [1 ]
Ishii, Youichi [1 ]
机构：
[1] Chuo Univ, Fac Sci & Engn, Dept Appl Chem, Bunkyo Ku, 1-13-27 Kasuga, Tokyo 1128551, Japan
来源：
TETRAHEDRON LETTERS | 2017年 / 58卷 / 33期
关键词：
Oxidation reactions; Oxidovanadium complexes; Perrhenate ions; Benzylic alcohols; Molecular oxygen; MOLECULAR-OXYGEN; VANADIUM COMPOUNDS; ELECTRON-TRANSFER; ALDEHYDES; PEROXIDE; CLEAVAGE; KETONES; REDOX; WATER; AIR;
D O I：
10.1016/j.tetlet.2017.07.034
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
An oxidovanadium(IV) complex having a perrhenato ligand [VO(ReO4)(4,4'-(t)Bubpy)(2)][0.25SO(4)center dot 0.5ReO(4)] (4,4'-(t)Bubpy = 4,4'-di-tert-butyl-2,2'-bipyridine) efficiently catalyzes not only dehydrogenative oxidation of benzylic and propargylic mono-alcohols but also oxidative C-C bond cleavage of meso-1,2-diaryl-1,2-ethanediols under atmospheric molecular oxygen, affording the corresponding carbonyl compounds in good yield. (C) 2017 Elsevier Ltd. All rights reserved.
引用
收藏
页码：3306 / 3310
页数：5
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