Saccharide derived dinuclear Cu(II) complex: An efficient catalyst for oxidation of catechol and benzylic alcohols

被引：5
|
作者：
Soni, Kiran [1 ]
Kumar, Anil [1 ]
Sah, Ajay K. [1 ]
机构：
[1] Birla Inst Technol & Sci, Dept Chem, Pilani 333031, Rajasthan, India
来源：
CATALYSIS COMMUNICATIONS | 2012年 / 17卷
关键词：
Glucopyranosylamine; Copper; Catecholase; TEMPO; Ionic liquid; Oxidation; SELECTIVE AEROBIC OXIDATION; COPPER(II) COMPLEXES; ALDEHYDES; LIGAND; ACETYLACETONATE; TETRANUCLEAR; TRINUCLEAR;
D O I：
10.1016/j.catcom.2011.10.018
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Catalytical aspect of 4,6-O-ethylidene-beta-D-glucopyranosylamine derived dinuclear Cu(II) complex has been explored. The complex exhibits good catecholase like activity and oxidizes model substrate 3,5-di-tert-butylcatechol to 3,5-di-tert-butyl-o-quinone. The complex also acts as selective catalyst to oxidize the primary and secondary alcohols to corresponding carbonyl compounds in excellent yield (65-82%) under mild conditions. (C) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码：95 / 98
页数：4
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