The reagent Et2AlX/CH2N2 in cyclopropanation of sterically hindered olefins, as well as oxygen- and nitrogen-containing unsaturated compounds

被引：0

作者：

I. R. Ramazanov

A. V. Yaroslavova

N. R. Yaubasarov

E. N. Gil’manova

U. M. Dzhemilev

机构：

[1] Russian Academy of Sciences,Institute of Petrochemistry and Catalysis

来源：

Russian Chemical Bulletin | 2019年 / 68卷

关键词：

organoaluminum compounds; diazomethane; aluminum carbenoids; cyclopropanation;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

A transition-metal-free method of cyclopropanation of sterically hindered olefins, substituted allylic alcohols, allylamines, and vinyl silyl ethers was developed using diazomethane in the presence of organic aluminum halides.

引用

页码：1869 / 1873

页数：4

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